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DC Field | Value | Language |
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dc.citation.endPage | 936 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 925 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 36 | - |
dc.contributor.author | Seong, Junmo | - |
dc.contributor.author | Jeong, Seok | - |
dc.contributor.author | Moon, Sung Wook | - |
dc.contributor.author | Lee, Seonghwan | - |
dc.contributor.author | Lim, Jaewoong | - |
dc.contributor.author | Sharma, Amitosh | - |
dc.contributor.author | Won, Somi | - |
dc.contributor.author | Baek, Seung Bin | - |
dc.contributor.author | Min, Seung Kyu | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-27T10:35:09Z | - |
dc.date.available | 2023-12-27T10:35:09Z | - |
dc.date.created | 2023-12-27 | - |
dc.date.issued | 2024-01 | - |
dc.description.abstract | Post-synthetic exchange serves as a potent technique to craft multivariate metal–organic frameworks (MOFs). These MOFs outperform in properties beyond the mere fusion of individual components. The post-synthetic ligand exchange (PLE) process in anisotropic 3D MOFs, which have pillared 2D layers, can cause a 1D contraction of the framework structure. This process can be effectively regulated by manipulating the temperature. At lower temperatures, the mixed building blocks form a microstructural MOF, which is homogeneous with a uniform distribution. However, as the temperature increases, the distribution transforms. It becomes heterogeneous, featuring a 2D concentric distribution of mixed building blocks. The reverse PLE process triggers a 1D expansion of the framework structure. This can create a heterogeneous microstructural MOF characterized by a 1D sandwiched distribution due to varying exchange kinetics between the layers. However, as temperatures increase, this layer selectivity diminishes, leading to a change of the building block distribution in the MOF structure. It evolves into another form of a heterogeneous microstructural MOF, this time exhibiting a 3D core–shell distribution. | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.36, no.2, pp.925 - 936 | - |
dc.identifier.doi | 10.1021/acs.chemmater.3c02815 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.scopusid | 2-s2.0-85181569046 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/67134 | - |
dc.identifier.wosid | 001148246000001 | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Multivariate Metal–Organic Frameworks Ranging from a Homogeneous Uniform Distribution to Heterogeneous 1D, 2D, and 3D Distributions of Mixed Building Blocks | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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