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| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 3600 | - |
| dc.citation.number | 16 | - |
| dc.citation.startPage | 3593 | - |
| dc.citation.title | CHEMISTRY OF MATERIALS | - |
| dc.citation.volume | 23 | - |
| dc.contributor.author | Lee, Kyu Tae | - |
| dc.contributor.author | Ramesh, T. N. | - |
| dc.contributor.author | Nan, F. | - |
| dc.contributor.author | Botton, G. | - |
| dc.contributor.author | Nazar, Linda F. | - |
| dc.date.accessioned | 2023-12-22T06:07:02Z | - |
| dc.date.available | 2023-12-22T06:07:02Z | - |
| dc.date.created | 2014-09-29 | - |
| dc.date.issued | 2011-08 | - |
| dc.description.abstract | New metastable olivine phases of sodium metal phosphates, Na[Mn 1-xMx]PO4 (M = Fe, Ca, Mg), nanorods are synthesized by a simple solid-state reaction at low temperature (≥100 °C) by means of a topotactic molten salt reaction that converts NH 4[Mn1-xMx]PO4•H2O (M = Fe, Ca, Mg) to Na[Mn1-xMx]PO4. Their crystal structures are characterized via XRD Rietveld refinement and electron diffraction. A full range of solid solution behavior was observed for olivine Na1-xMn0.5Fe0.5PO4, in contrast to that of LiMPO4 (M = Fe, Mn) olivine materials, and is ascribed to ion size effects. The solid solution behavior of NaMn0.5Fe 0.5PO4 was confirmed by electrochemical characterization. | - |
| dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.23, no.16, pp.3593 - 3600 | - |
| dc.identifier.doi | 10.1021/cm200450y | - |
| dc.identifier.issn | 0897-4756 | - |
| dc.identifier.scopusid | 2-s2.0-80051759616 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6709 | - |
| dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80051759616 | - |
| dc.identifier.wosid | 000293758900004 | - |
| dc.language | 영어 | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Topochemical Synthesis of Sodium Metal Phosphate Olivines for Sodium-Ion Batteries | - |
| dc.type | Article | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.subject.keywordAuthor | olivine | - |
| dc.subject.keywordAuthor | Na-ion battery | - |
| dc.subject.keywordAuthor | topotactic | - |
| dc.subject.keywordAuthor | low-temperature synthesis | - |
| dc.subject.keywordAuthor | cathode material | - |
| dc.subject.keywordPlus | ELECTROCHEMICAL INSERTION | - |
| dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
| dc.subject.keywordPlus | RECHARGEABLE BATTERIES | - |
| dc.subject.keywordPlus | CATHODE MATERIALS | - |
| dc.subject.keywordPlus | FLUOROPHOSPHATE | - |
| dc.subject.keywordPlus | LITHIUM | - |
| dc.subject.keywordPlus | NA | - |
| dc.subject.keywordPlus | PHASES | - |
| dc.subject.keywordPlus | SPINEL | - |
| dc.subject.keywordPlus | CARBON | - |
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