dc.citation.endPage |
2822 |
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dc.citation.number |
13 |
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dc.citation.startPage |
2818 |
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dc.citation.title |
CRYSTENGCOMM |
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dc.citation.volume |
16 |
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dc.contributor.author |
Kim, Jae-Kwang |
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dc.date.accessioned |
2023-12-22T02:36:44Z |
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dc.date.available |
2023-12-22T02:36:44Z |
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dc.date.created |
2014-09-30 |
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dc.date.issued |
2014-07 |
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dc.description.abstract |
A short synthesis time and high tap density are key conditions for the commercialization of electrode materials. Carbon coated three-dimensional porous LiFePO4 microspheres are synthesized by a supercritical and spray-dry combination method in a significantly short processing time (about 10 min). The three-dimensional (3D) porous morphology is composed of nanocrystallites tightly compacted to form three-dimensional electronic and ionic channels, which enhances their electrochemical properties. The obtained porous LiFePO4 microspheres are intensively analyzed by XRD, SEM, TGA, and FT-IR techniques. The porous microspheres, which are 60 μm in size, show uniform morphology with the carbon coating. Moreover, at a 0.1 C rate the 3D porous microspheres of LiFePO4 exhibit a high initial capacity with a high tap density (1.7 g cm-3) and high active material content (~90% without carbon), which corresponds to 94% and 79% of the theoretical capacity at 0.1 and 1 C. |
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dc.identifier.bibliographicCitation |
CRYSTENGCOMM, v.16, no.13, pp.2818 - 2822 |
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dc.identifier.doi |
10.1039/c3ce42264j |
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dc.identifier.issn |
1466-8033 |
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dc.identifier.scopusid |
2-s2.0-84897732014 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/6692 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84897732014 |
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dc.identifier.wosid |
000332466800034 |
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dc.language |
영어 |
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dc.publisher |
ROYAL SOC CHEMISTRY |
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dc.title |
Supercritical synthesis in combination with a spray process for 3D porous microsphere lithium iron phosphate |
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dc.type |
Article |
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dc.relation.journalWebOfScienceCategory |
Chemistry, Multidisciplinary; Crystallography |
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dc.relation.journalResearchArea |
Chemistry; Crystallography |
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dc.description.journalRegisteredClass |
scie |
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dc.description.journalRegisteredClass |
scopus |
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