dc.citation.endPage |
3163 |
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dc.citation.number |
15 |
- |
dc.citation.startPage |
3161 |
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dc.citation.title |
ORGANOMETALLICS |
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dc.citation.volume |
17 |
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dc.contributor.author |
Jeon, YM |
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dc.contributor.author |
Park, Soojin |
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dc.contributor.author |
Heo, J |
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dc.contributor.author |
Kim, K |
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dc.date.accessioned |
2023-12-22T12:36:02Z |
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dc.date.available |
2023-12-22T12:36:02Z |
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dc.date.created |
2014-09-26 |
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dc.date.issued |
1998-07 |
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dc.description.abstract |
Using the new ancillary ligand 2,2'-ethylenebis(N,N'-(triisopropylsilyl)anilinido) ((EBTP)-P-i, 1), the zirconium complexes ((EBTP)-P-i)ZrCl2 (2) and ((EBTP)-P-i)-ZrMe2 (3) have been prepared. X-ray crystal structures and H-1 NMR spectra of 2 and 3 reveal that they both have a C-2-symmetric conformation. Complexes 2, activated by MAO, and 3, activated by either MAO or B(C6F5)(3) are good catalysts for the polymerization of terminal olefins. In. particular, the polymerization of 1-hexene catalyzed by 3/B(C6F5)(3) at low temperature is living. |
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dc.identifier.bibliographicCitation |
ORGANOMETALLICS, v.17, no.15, pp.3161 - 3163 |
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dc.identifier.doi |
10.1021/om980249d |
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dc.identifier.issn |
0276-7333 |
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dc.identifier.scopusid |
2-s2.0-0006323422 |
- |
dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/6610 |
- |
dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0006323422 |
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dc.identifier.wosid |
000075154600012 |
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dc.language |
영어 |
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dc.publisher |
AMER CHEMICAL SOC |
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dc.title |
Zirconium complexes with the new ancillary diamido ligand 2,2′-ethylenebis(N,N′-(triisopropylsilyl)anilinido)2-: Syntheses, structures, and living α-olefin polymerization activities |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
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