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DC Field | Value | Language |
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dc.citation.number | 37 | - |
dc.citation.title | SMALL | - |
dc.citation.volume | 15 | - |
dc.contributor.author | Sinha, Soumyadeep | - |
dc.contributor.author | Didwal, Pravin N. | - |
dc.contributor.author | Nandi, Dip K. | - |
dc.contributor.author | Verma, Rakesh | - |
dc.contributor.author | Cho, Jae Yu | - |
dc.contributor.author | Kim, Soo-Hyun | - |
dc.contributor.author | Park, Chan-Jin | - |
dc.contributor.author | Heo, Jaeyeong | - |
dc.date.accessioned | 2023-12-21T18:40:30Z | - |
dc.date.available | 2023-12-21T18:40:30Z | - |
dc.date.created | 2022-12-23 | - |
dc.date.issued | 2019-09 | - |
dc.description.abstract | Although sodium-ion batteries (SIBs) are considered promising alternatives to their Li counterparts, they still suffer from challenges like slow kinetics of the sodiation process, large volume change, and inferior cycling stability. On the other hand, the presence of additional reversible conversion reactions makes the metal compounds the preferred anode materials over carbon. However, conductivity and crystallinity of such materials often play the pivotal role in this regard. To address these issues, atomic layer deposited double-anion-based ternary zinc oxysulfide (ZnOS) thin films as an anode material in SIBs are reported. Electrochemical studies are carried out with different O/(O+S) ratios, including O-rich and S-rich crystalline ZnOS along with the amorphous phase. Amorphous ZnOS with the O/(O+S) ratio of approximate to 0.4 delivers the most stable and considerably high specific (and volumetric) capacities of 271.9 (approximate to 1315.6 mAh cm(-3)) and 173.1 mAh g(-1) (approximate to 837.7 mAh cm(-3)) at the current densities of 500 and 1000 mA g(-1), respectively. A dominant capacitive-controlled contribution of the amorphous ZnOS anode indicates faster electrochemical reaction kinetics. An electrochemical reaction mechanism is also proposed via X-ray photoelectron spectroscopy analyses. A comparison of the cycling stability further establishes the advantage of this double-anion-based material over pristine ZnO and ZnS anodes. | - |
dc.identifier.bibliographicCitation | SMALL, v.15, no.37 | - |
dc.identifier.doi | 10.1002/smll.201900595 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.scopusid | 2-s2.0-85070112446 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/64077 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/smll.201900595 | - |
dc.identifier.wosid | 000480126400001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Revealing the Simultaneous Effects of Conductivity and Amorphous Nature of Atomic-Layer-Deposited Double-Anion-Based Zinc Oxysulfide as Superior Anodes in Na-Ion Batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | amorphous phase | - |
dc.subject.keywordAuthor | atomic-layer deposition | - |
dc.subject.keywordAuthor | cycling stability | - |
dc.subject.keywordAuthor | Na-ion batteries | - |
dc.subject.keywordAuthor | ZnOS anodes | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE ANODE | - |
dc.subject.keywordPlus | ENHANCED ELECTROCHEMICAL PERFORMANCE | - |
dc.subject.keywordPlus | POROUS CARBON POLYHEDRA | - |
dc.subject.keywordPlus | BINDER-FREE ANODE | - |
dc.subject.keywordPlus | LITHIUM-ION | - |
dc.subject.keywordPlus | LI-ION | - |
dc.subject.keywordPlus | THIN-FILM | - |
dc.subject.keywordPlus | PHOTOELECTRON-SPECTROSCOPY | - |
dc.subject.keywordPlus | SODIUM STORAGE | - |
dc.subject.keywordPlus | DOPED CARBON | - |
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