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Schultz, Thomas
CRASY (Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy
  • Ultrafast spectroscopy
  • High-resolution spectroscopy
  • Photochemistry


Time-resolved photoelectron spectroscopy of the allyl radical: The lifetimes of the ultraviolet bands

DC Field Value Language Schultz, Thomas ko Fischer, I. ko 2014-09-23T07:01:51Z - 2014-09-18 ko 1998 ko
dc.identifier.citation JOURNAL OF CHEMICAL PHYSICS, v.109, no.14, pp.5812 - 5822 ko
dc.identifier.issn 0021-9606 ko
dc.identifier.uri -
dc.description.abstract We report [1+1 ′] picosecond time-resolved pump-probe photoelectron spectra of the UV bands of the allyl radical. The experiments are performed in a molecular beam of allyl radicals, generated by supersonic jet flash pyrolysis. Photoelectron spectroscopy in a magnetic bottle is shown to be a suitable method for investigating the photophysics of organic radicals. Lifetimes were obtained for all vibronic bands between 250 and 238 nm previously assigned by MPI spectroscopy to the electronically excited B 2A 1, C 2B 1, and D 2B 2 states, with values ranging from 20 ps to 9 ps. The nonradiative decay is due to internal conversion to the electronic ground state. Information on the structure of the allyl cation is deduced from the photoelectron spectrum. ko
dc.description.statementofresponsibility open -
dc.language 영어 ko
dc.publisher AMER INST PHYSICS ko
dc.title Time-resolved photoelectron spectroscopy of the allyl radical: The lifetimes of the ultraviolet bands ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-0001213457 ko
dc.identifier.wosid 000076216900014 ko
dc.type.rims ART ko
dc.description.wostc 42 *
dc.description.scopustc 39 * 2015-05-06 * 2014-09-18 *
dc.identifier.doi 10.1063/1.477203 ko
dc.identifier.url ko
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