dc.citation.endPage |
5822 |
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dc.citation.number |
14 |
- |
dc.citation.startPage |
5812 |
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dc.citation.title |
JOURNAL OF CHEMICAL PHYSICS |
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dc.citation.volume |
109 |
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dc.contributor.author |
Schultz, Thomas |
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dc.contributor.author |
Fischer, I. |
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dc.date.accessioned |
2023-12-22T12:36:41Z |
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dc.date.available |
2023-12-22T12:36:41Z |
- |
dc.date.created |
2014-09-18 |
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dc.date.issued |
1998 |
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dc.description.abstract |
We report [1+1 ′] picosecond time-resolved pump-probe photoelectron spectra of the UV bands of the allyl radical. The experiments are performed in a molecular beam of allyl radicals, generated by supersonic jet flash pyrolysis. Photoelectron spectroscopy in a magnetic bottle is shown to be a suitable method for investigating the photophysics of organic radicals. Lifetimes were obtained for all vibronic bands between 250 and 238 nm previously assigned by MPI spectroscopy to the electronically excited B 2A 1, C 2B 1, and D 2B 2 states, with values ranging from 20 ps to 9 ps. The nonradiative decay is due to internal conversion to the electronic ground state. Information on the structure of the allyl cation is deduced from the photoelectron spectrum. |
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dc.identifier.bibliographicCitation |
JOURNAL OF CHEMICAL PHYSICS, v.109, no.14, pp.5812 - 5822 |
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dc.identifier.doi |
10.1063/1.477203 |
- |
dc.identifier.issn |
0021-9606 |
- |
dc.identifier.scopusid |
2-s2.0-0001213457 |
- |
dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/6314 |
- |
dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0001213457 |
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dc.identifier.wosid |
000076216900014 |
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dc.language |
영어 |
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dc.publisher |
AMER INST PHYSICS |
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dc.title |
Time-resolved photoelectron spectroscopy of the allyl radical: The lifetimes of the ultraviolet bands |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
- |