dc.citation.number |
9 |
- |
dc.citation.title |
JOURNAL OF CHEMICAL PHYSICS |
- |
dc.citation.volume |
122 |
- |
dc.contributor.author |
Zierhut, M |
- |
dc.contributor.author |
Noller, B |
- |
dc.contributor.author |
Schultz, Thomas |
- |
dc.contributor.author |
Fischer, I |
- |
dc.date.accessioned |
2023-12-22T10:39:50Z |
- |
dc.date.available |
2023-12-22T10:39:50Z |
- |
dc.date.created |
2014-09-19 |
- |
dc.date.issued |
2005 |
- |
dc.description.abstract |
The excited state decay of the hydrocarbon radicals ethyl, C 2H 5; propargyl, C 3H 3; and benzyl, C 7H 7 was investigated by femtosecond time-resolved photoionization. Radicals were generated by flash pyrolysis of n-propyl nitrite, propargyl bromide, and toluene, respectively. It is shown that the 2 2A ′ (3s) Rydberg state of ethyl excited at 250 nm decays with a time constant of 20 fs. No residual signal was observed at longer delay times. For the 3 2B 1 state of propargyl excited at 255 nm a slower decay with a time constant 50±10 fs was determined. The 4 2B 2 state of benzyl excited at 255 nm decays within 150±30 fs. |
- |
dc.identifier.bibliographicCitation |
JOURNAL OF CHEMICAL PHYSICS, v.122, no.9 |
- |
dc.identifier.doi |
10.1063/1.1857475 |
- |
dc.identifier.issn |
0021-9606 |
- |
dc.identifier.scopusid |
2-s2.0-22944445465 |
- |
dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/6265 |
- |
dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=22944445465 |
- |
dc.identifier.wosid |
000227483300023 |
- |
dc.language |
영어 |
- |
dc.publisher |
AMER INST PHYSICS |
- |
dc.title |
Excited-state decay of hydrocarbon radicals, investigated by femtosecond time-resolved photoionization: Ethyl, propargyl, and benzyl |
- |
dc.type |
Article |
- |
dc.description.journalRegisteredClass |
scopus |
- |