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DC Field | Value | Language |
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dc.citation.number | 192 | - |
dc.citation.startPage | e64978 | - |
dc.citation.title | JOVE-JOURNAL OF VISUALIZED EXPERIMENTS | - |
dc.citation.volume | 192 | - |
dc.contributor.author | Park, Jihyun | - |
dc.contributor.author | Ha, Junsu | - |
dc.contributor.author | Moon, Hoi Ri | - |
dc.date.accessioned | 2023-12-21T13:06:38Z | - |
dc.date.available | 2023-12-21T13:06:38Z | - |
dc.date.created | 2023-04-06 | - |
dc.date.issued | 2023-02 | - |
dc.description.abstract | Because of their designability and unprecedented synergistic effects, core-shell metal -organic frameworks (MOFs) have been actively examined recently. However, the synthesis of single-crystalline core-shell MOFs is very challenging, and thus a limited number of examples have been reported. Here, we suggest a method of synthesizing single-crystalline HKUST-1@MOF-5 core-shells, which is HKUST-1 at the center of MOF-5. Through the computational algorithm, this pair of MOFs was predicted to have the matched lattice parameters and chemical connection points at the interface. To construct the core-shell structure, we prepared the octahedral-and cubic-shaped HKUST-1 crystals as a core MOF, in which the (111) and (001) facets were mainly exposed, respectively. Via the sequential reaction, the MOF-5 shell was well-grown on the exposed surface, showing a seamless connect interface, which resulted in the successful synthesis of single-crystalline HKUST-1@MOF-5. Their pure phase formation was proved by optical microscopic images and powder X-ray diffraction (PXRD) patterns. This method presents the potential of and insights into the single -crystalline core-shell synthesis with different kinds of MOFs. | - |
dc.identifier.bibliographicCitation | JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, v.192, no.192, pp.e64978 | - |
dc.identifier.doi | 10.3791/64978 | - |
dc.identifier.issn | 1940-087X | - |
dc.identifier.scopusid | 2-s2.0-85149041555 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/62563 | - |
dc.identifier.wosid | 000946321000026 | - |
dc.language | 영어 | - |
dc.publisher | JOURNAL OF VISUALIZED EXPERIMENTS | - |
dc.title | Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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