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DC Field | Value | Language |
---|---|---|
dc.citation.number | 20 | - |
dc.citation.startPage | 2300240 | - |
dc.citation.title | SMALL | - |
dc.citation.volume | 19 | - |
dc.contributor.author | Ha, Miran | - |
dc.contributor.author | Thangavel, Pandiarajan | - |
dc.contributor.author | Dang, Ngoc Kim | - |
dc.contributor.author | Kim, Dong Yeon | - |
dc.contributor.author | Sultan, Siraj | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.contributor.author | Kim, Kwang S. | - |
dc.date.accessioned | 2023-12-21T12:40:45Z | - |
dc.date.available | 2023-12-21T12:40:45Z | - |
dc.date.created | 2023-03-21 | - |
dc.date.issued | 2023-05 | - |
dc.description.abstract | Electrocatalysts facilitating chlorine evolution reaction (ClER) play a vital role in chlor–alkali industries. Owing to a huge amount of chlorine consumed worldwide, inexpensive high-performing catalysts for Cl2 production are highly demanded. Here, a superb ClER catalyst fabricated through uniform dispersion of Pt single atoms (SAs) in C2N2 moieties of N-doped graphene (denoted as Pt-1) is presented, which demonstrates near 100% exclusive ClER selectivity, long-term durability, extraordinary Cl2 production rate (3500 mmol h−1 gPt−1), and >140 000-fold increased mass activity over industrial electrodes in acidic medium. Excitingly, at the typical chlor–alkali industries’ operating temperature (80 °C), Pt-1 supported on carbon paper electrode requires a near thermoneutral ultralow overpotential of 5 mV at 1 mA cm−2 current density to initiate the ClER, consistent with the predicted density functional theory (DFT) calculations. Altogether these results show the promising electrocatalyst of Pt-1 toward ClER. | - |
dc.identifier.bibliographicCitation | SMALL, v.19, no.20, pp.2300240 | - |
dc.identifier.doi | 10.1002/smll.202300240 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.scopusid | 2-s2.0-85148344608 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/62488 | - |
dc.identifier.wosid | 000936721000001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY | - |
dc.title | High-Performing Atomic Electrocatalyst for Chlorine Evolution Reaction | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary;Chemistry, Physical;Nanoscience & Nanotechnology;Materials Science, Multidisciplinary;Physics, Applied;Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry;Science & Technology - Other Topics;Materials Science;Physics | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | chlorine evolution reaction | - |
dc.subject.keywordAuthor | electrocatalysts | - |
dc.subject.keywordAuthor | metal single atom catalysts | - |
dc.subject.keywordAuthor | N-doped graphene | - |
dc.subject.keywordAuthor | Pt single atoms | - |
dc.subject.keywordPlus | CHLORALKALI PROCESS | - |
dc.subject.keywordPlus | ACTIVE-SITES | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | HISTORY | - |
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