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dc.citation.number 2 -
dc.citation.startPage 024503 -
dc.citation.title JOURNAL OF CHEMICAL PHYSICS -
dc.citation.volume 137 -
dc.contributor.author Buchner, Franziska -
dc.contributor.author Ritze, Hans-Hermann -
dc.contributor.author Beutler, Marcus -
dc.contributor.author Schultz, Thomas -
dc.contributor.author Hertel, Ingolf V. -
dc.contributor.author Luebcke, Andrea -
dc.date.accessioned 2023-12-22T05:06:48Z -
dc.date.available 2023-12-22T05:06:48Z -
dc.date.created 2014-09-19 -
dc.date.issued 2012-07 -
dc.description.abstract Time-resolved liquid jet photoelectron spectroscopy was used to explore the excited state dynamics at the liquid water surface in the presence of alkali cations. The data were evaluated with the help of ab initio calculations on alkali-water clusters and an extension of these results on the basis of the dielectric continuum model: 160nm, sub-20fs vacuum ultraviolet pulses excite water molecules in the solvent shell of Na + or K + cations and evolve into a transient hydrated complex of alkali-ion and electron. The vertical ionization energy of this transient is about 2.5eV, significantly smaller than that of the solvated electron. ⓒ 2012 American Institute of Physics. -
dc.identifier.bibliographicCitation JOURNAL OF CHEMICAL PHYSICS, v.137, no.2, pp.024503 -
dc.identifier.doi 10.1063/1.4732582 -
dc.identifier.issn 0021-9606 -
dc.identifier.scopusid 2-s2.0-84863936067 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/6233 -
dc.identifier.url https://aip.scitation.org/doi/10.1063/1.4732582 -
dc.identifier.wosid 000306361000024 -
dc.language 영어 -
dc.publisher AMER INST PHYSICS -
dc.title Role of alkali cations for the excited state dynamics of liquid water near the surface -
dc.type Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -

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