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DC Field | Value | Language |
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dc.citation.endPage | 124 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 120 | - |
dc.citation.title | CHEMSUSCHEM | - |
dc.citation.volume | 11 | - |
dc.contributor.author | Kim, Kwiyong | - |
dc.contributor.author | Lee, Seung Jong | - |
dc.contributor.author | Kim, Dong-Yeon | - |
dc.contributor.author | Yoo, Chung-Yul | - |
dc.contributor.author | Choi, Jang Wook | - |
dc.contributor.author | Kim, Jong-Nam | - |
dc.contributor.author | Woo, Youngmin | - |
dc.contributor.author | Yoon, Hyung Chul | - |
dc.contributor.author | Han, Jong-In | - |
dc.date.accessioned | 2023-12-21T21:12:04Z | - |
dc.date.available | 2023-12-21T21:12:04Z | - |
dc.date.created | 2023-02-13 | - |
dc.date.issued | 2018-01 | - |
dc.description.abstract | Lithium-mediated reduction of dinitrogen is a promising method to evade electron-stealing hydrogen evolution, a critical challenge which limits faradaic efficiency (FE) and thus hinders the success of traditional protic-solvent-based ammonia electro-synthesis. A viable implementation of the lithium-mediated pathway using lithium-ion conducting glass ceramics involves i)lithium deposition, ii)nitridation, and iii)ammonia formation. Ammonia was successfully synthesized from molecular nitrogen and water, yielding a maximum FE of 52.3%. With an ammonia synthesis rate comparable to previously reported approaches, the fairly high FE demonstrates the possibility of using this nitrogen fixation strategy as a substitute for firmly established, yet exceedingly complicated and expensive technology, and in so doing represents a next-generation energy storage system. | - |
dc.identifier.bibliographicCitation | CHEMSUSCHEM, v.11, no.1, pp.120 - 124 | - |
dc.identifier.doi | 10.1002/cssc.201701975 | - |
dc.identifier.issn | 1864-5631 | - |
dc.identifier.scopusid | 2-s2.0-85034779123 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/62104 | - |
dc.identifier.wosid | 000419685900010 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Electrochemical Synthesis of Ammonia from Water and Nitrogen: A Lithium-Mediated Approach Using Lithium-Ion Conducting Glass Ceramics | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Green & Sustainable Science & Technology | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | ammonia | - |
dc.subject.keywordAuthor | faradic efficiency | - |
dc.subject.keywordAuthor | lithium | - |
dc.subject.keywordAuthor | lithium nitrides | - |
dc.subject.keywordAuthor | nitrogen fixation | - |
dc.subject.keywordPlus | ATMOSPHERIC-PRESSURE | - |
dc.subject.keywordPlus | AMBIENT-TEMPERATURE | - |
dc.subject.keywordPlus | CARBON | - |
dc.subject.keywordPlus | N-2 | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | AIR | - |
dc.subject.keywordPlus | BATTERY | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | NH3 | - |
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