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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1264 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 1259 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY LETTERS | - |
dc.citation.volume | 14 | - |
dc.contributor.author | Sugiyama, Hironobu | - |
dc.contributor.author | Nakamura, Nobuhiro | - |
dc.contributor.author | Watanabe, Satoru | - |
dc.contributor.author | Kim, Junghwan | - |
dc.contributor.author | Kitano, Masaaki | - |
dc.contributor.author | Hosono, Hideo | - |
dc.date.accessioned | 2023-12-21T13:08:34Z | - |
dc.date.available | 2023-12-21T13:08:34Z | - |
dc.date.created | 2023-02-14 | - |
dc.date.issued | 2023-01 | - |
dc.description.abstract | Methanol, a raw material for C1 chemistry, is industrially produced under harsh conditions using Cu/ZnO-based catalysts. The synthesis of methanol under mild conditions is a challenging subject using an improved catalyst. Here, Zn1-xSixO (ZSO) nanoparticles were synthesized by a thermal plasma method, and their work function and carrier concentration could be tuned by the Zn:Si ratio. The electrically conductive ZSO nanoparticles with a low work function enhanced the donation of electrons to loaded Cu and significantly promoted hydrogenation of CO to methanol, whereas insulating ZSO nanoparticles with a similar low work function did not. These results reveal that efficient electronic promotion by the transfer of electrons from a support to loaded Cu plays a key role in low-temperature methanol synthesis. | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY LETTERS, v.14, no.5, pp.1259 - 1264 | - |
dc.identifier.doi | 10.1021/acs.jpclett.2c03427 | - |
dc.identifier.issn | 1948-7185 | - |
dc.identifier.scopusid | 2-s2.0-85147213981 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/62007 | - |
dc.identifier.wosid | 000928253100001 | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Electronic Promotion of Methanol Synthesis over Cu-Loaded ZnO-Based Catalysts | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical;Nanoscience & Nanotechnology;Materials Science, Multidisciplinary;Physics, Atomic, Molecular & Chemical | - |
dc.relation.journalResearchArea | Chemistry;Science & Technology - Other Topics;Materials Science;Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | AMMONIA-SYNTHESIS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | HYDROGENATION | - |
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