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Kim, Guntae
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Research Interests
  • Solid Oxide Fuel Cells (SOFCs)& SOE, PEMFC, metal-air batteries, Metal-CO2 system, Catalyst for DRM

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Enhancing sulfur tolerance of a Ni-YSZ anode through BaZr 0.1Ce0.7Y0.1Yb0.1O 3?δ infiltration

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Title
Enhancing sulfur tolerance of a Ni-YSZ anode through BaZr 0.1Ce0.7Y0.1Yb0.1O 3?δ infiltration
Author
Sengodan, SivaprakashLiu, MingfeiLim, Tak-HyoungShin, JeeyoungLiu, MeilinKim, Guntae
Issue Date
2014-05
Publisher
ELECTROCHEMICAL SOC INC
Citation
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.161, no.5, pp.F668 - F673
Abstract
In this study, sulfur tolerance of a conventional Ni-yttria stabilized zirconia (Ni-YSZ) anode for solid oxide fuel cells is significantly improved by surface modification. The Ni-YSZ anode modified by the infiltration of BaZr 0.1Ce0.7Y0.1Yb0.1O 3?δ (BZCYYb) demonstrates stable performance in a sulfur-containing H2 fuel over 500 hours. In contrast, the bare Ni-YSZ anode without surface modification degrades drastically when exposed to the sulfur-containing H2 fuel. This implies that the BZCYYb coating is an excellent catalyst for surface modification of the conventional Ni-YSZ anode. A single step infiltration of BZCYYb into the Ni-YSZ anode was sufficient to provide good sulfur tolerance.
URI
https://scholarworks.unist.ac.kr/handle/201301/6135
URL
http://jes.ecsdl.org/content/161/5/F668
DOI
10.1149/2.068405jes
ISSN
0013-4651
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