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DC Field | Value | Language |
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dc.citation.number | 15 | - |
dc.citation.startPage | e202117815 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 61 | - |
dc.contributor.author | Meng, Yongqiang | - |
dc.contributor.author | Fan, Jingbiao | - |
dc.contributor.author | Wang, Meihui | - |
dc.contributor.author | Gong, Wenbin | - |
dc.contributor.author | Zhang, Jinping | - |
dc.contributor.author | Ma, Junpeng | - |
dc.contributor.author | Mi, Hongyu | - |
dc.contributor.author | Huang, Yan | - |
dc.contributor.author | Yang, Shu | - |
dc.contributor.author | Ruoff, Rodney S. | - |
dc.contributor.author | Geng, Jianxin | - |
dc.date.accessioned | 2023-12-21T14:18:52Z | - |
dc.date.available | 2023-12-21T14:18:52Z | - |
dc.date.created | 2022-03-03 | - |
dc.date.issued | 2022-04 | - |
dc.description.abstract | Graphene has demonstrated broad applications due to its prominent properties. Its molecular structure makes graphene achiral. Here, we propose a direct way to prepare chiral graphene by transferring chiral structural conformation from chiral conjugated amino acids onto graphene basal plane through pi-pi interaction followed by thermal fusion. Using atomic resolution transmission electron microscopy, we estimated an areal coverage of the molecular imprints (chiral regions) up to 64 % on the basal plane of graphene (grown by chemical vapor deposition). The high concentration of molecular imprints in their single layer points to a close packing of the deposited amino acid molecules prior to "thermal fusion". Such "molecular chirality-encoded graphene" was tested as an electrode in electrochemical enantioselective recognition. The chirality-encoded graphene might find use for other chirality-related studies and the encoding procedure might be extended to other two-dimensional materials. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.61, no.15, pp.e202117815 | - |
dc.identifier.doi | 10.1002/anie.202117815 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-85124829789 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/61155 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/anie.202117815 | - |
dc.identifier.wosid | 000756137700001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Encoding Enantiomeric Molecular Chiralities on Graphene Basal Planes | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Amino Acids | - |
dc.subject.keywordAuthor | Chiral Recognition | - |
dc.subject.keywordAuthor | Chirality | - |
dc.subject.keywordAuthor | Composite | - |
dc.subject.keywordAuthor | Graphene | - |
dc.subject.keywordPlus | RECOGNITION | - |
dc.subject.keywordPlus | HYBRID | - |
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