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DC Field | Value | Language |
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dc.citation.endPage | 1756 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 1749 | - |
dc.citation.title | ORGANOMETALLICS | - |
dc.citation.volume | 16 | - |
dc.contributor.author | Lee, SS | - |
dc.contributor.author | Lee, TY | - |
dc.contributor.author | Choi, DS | - |
dc.contributor.author | Lee, JS | - |
dc.contributor.author | Chung, YK | - |
dc.contributor.author | Lee, SW | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-22T12:37:38Z | - |
dc.date.available | 2023-12-22T12:37:38Z | - |
dc.date.created | 2014-09-12 | - |
dc.date.issued | 1997-04 | - |
dc.description.abstract | New thiophene manganese derivatives, [(2-R1-C4H3S)Mn(CO)3]+ 1(sil) (R1 = Si(OCH2-CH2)3N) and 1(Mn) (R1 = (C6H6)Mn(CO)3), have been synthesized and their reaction with nucleophiles studied. Except for the Grignard reagent, nucleophiles (Nu- = H-, -CN, -P(O)(OR)2 (R = Me, Ph)) usually attack the C5 position. Grignard reagents attack the sulfur atom to yield manganese S-R-thiophene carbonyls 3. To compare the reactivities of 1(sil) and 1(Mn) with that of (thiophene)Mn(CO)3 + with respect to Grignard reagent addition, the known compounds [(thiophene)Mn(CO)3]+ (thiophene = thiophene, 2-methylthiophene, 2,5-dimethylthiophene) have been synthesized and their reaction with Grignard reagents studied. In all cases, S-R-thiophene manganese carbonyls 3 were obtained as a sole product. Refluxing 3 (R = Ph, p-tolyl, 2-thienyl) with Me3NO in benzene yielded diaryl sulfide. Treatment of 3 with NOBF4 in CH2Cl2 led to S-R-thiophenium-manganese dicarbonyl nitrosyl cations 4. Photolysis of 4 in acetone gave rise to S-R-thiophenium 5 in high yields. The molecular structures of [{2-exo-P(O)(OMe)2η4-C4H 3S}Mn(CO)3] (2(sil,P(O)(OMe)2)), [S-Ph-η4-2-{(η5-C6H 6)Mn(CO)3}SC4H3]Mn(CO)3 (3(Mn,Ph)), and [p-CH3C6H5-S-2-CH3C 4H3] (5(Me,p-tolyl)) have been determined by X-ray studies. | - |
dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.16, no.8, pp.1749 - 1756 | - |
dc.identifier.doi | 10.1021/om970031b | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.scopusid | 2-s2.0-0001635894 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6102 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0001635894 | - |
dc.identifier.wosid | A1997WU31800033 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Manganese thiophene tricarbonyl complexes: Nucleophilic addition to sulfur and synthesis of thiophenium salts | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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