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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 5726 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 5718 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 67 | - |
dc.contributor.author | Shim, SC | - |
dc.contributor.author | Kim, Dong Suk | - |
dc.contributor.author | Yoo, DJ | - |
dc.contributor.author | Wada, T | - |
dc.contributor.author | Inoue, Y | - |
dc.date.accessioned | 2023-12-22T11:37:10Z | - |
dc.date.available | 2023-12-22T11:37:10Z | - |
dc.date.created | 2022-12-10 | - |
dc.date.issued | 2002-08 | - |
dc.description.abstract | Highly diastereodifferentiating bimolecular asymmetric photoreaction was achieved in the photosensitized polar addition of methanol to (R)-(+)-limonene. The diastereomeric excess (de) of the photoadduct could be controlled and fine-tuned by changing the internal/external factors such as solvent polarity, reaction temperature, and structure of the sensitizers. The de increased from 23% obtained upon xylene photosensitization in pure methanol at room temperature to >96% upon singlet sensitization with methyl benzoate at -75 degreesC in 0.5 M methanol/diethyl ether solution. | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.67, no.16, pp.5718 - 5726 | - |
dc.identifier.doi | 10.1021/jo025782o | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.scopusid | 2-s2.0-0037047509 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/60211 | - |
dc.identifier.wosid | 000177318300034 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Diastereoselectivity control in photosensitized addition of methanol to (R)-(+)-limonene | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CIS-TRANS-PHOTOISOMERIZATION | - |
dc.subject.keywordPlus | PHOTOCHEMICAL-REACTIONS | - |
dc.subject.keywordPlus | ENANTIODIFFERENTIATING PHOTOISOMERIZATION | - |
dc.subject.keywordPlus | ASYMMETRIC PHOTOCHEMISTRY | - |
dc.subject.keywordPlus | PRODUCT CHIRALITY | - |
dc.subject.keywordPlus | ENANTIOSELECTIVE SYNTHESIS | - |
dc.subject.keywordPlus | SIMPLE ALKENES | - |
dc.subject.keywordPlus | TERTIARY-AMINES | - |
dc.subject.keywordPlus | CYCLO-OCTENE | - |
dc.subject.keywordPlus | SOLID-STATE | - |
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