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Cho, Jaeheung
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Nanozyme Based on Porphyrinic Metal-Organic Framework for Electrocatalytic CO2 Reduction

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dc.contributor.author Lee, Junghye ko
dc.contributor.author Choi, Hansaem ko
dc.contributor.author Mun, Jinhong ko
dc.contributor.author Jin, Eunji ko
dc.contributor.author Lee, Soochan ko
dc.contributor.author Nam, Joohan ko
dc.contributor.author Umer, Muhammad ko
dc.contributor.author Cho, Jaeheung ko
dc.contributor.author Lee, Geunsik ko
dc.contributor.author Kwon, Youngkook ko
dc.contributor.author Choe, Wonyoung ko
dc.date.available 2022-11-23T09:54:34Z -
dc.date.created 2022-11-04 ko
dc.date.issued 2022-10 ko
dc.identifier.citation SMALL STRUCTURES ko
dc.identifier.issn 2688-4062 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/60045 -
dc.description.abstract Mimicry of natural enzyme systems is an important approach for catalyst design. To create an enzyme-inspired catalyst, it is essential to mimic both the active center and the second coordination sphere. Metal-organic frameworks (MOFs), an emerging class of porous materials, are ideal candidates for heterogeneous catalysts because their versatile building blocks confer a high level of structural tunability, and the chemical environment surrounding the active center can be controlled at the molecular level. Herein, a new 2D porphyrinic MOF, PPF-100, constructed from a nonplanar saddle-distorted porphyrin linker and a Cu paddle-wheel metal node is reported. The strategic introduction of ethyl substituents allows not only to mimic the active center and second coordination sphere but also to increase the catalytic selectivity while completely inhibiting H-2 generation in the CO2 reduction reaction. ko
dc.language 영어 ko
dc.publisher WILEY ko
dc.title Nanozyme Based on Porphyrinic Metal-Organic Framework for Electrocatalytic CO2 Reduction ko
dc.type ARTICLE ko
dc.identifier.wosid 000866640300001 ko
dc.type.rims ART ko
dc.identifier.doi 10.1002/sstr.202200087 ko
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