Related Researcher

Author's Photo

Cho, Jaeheung
Research Interests


Nanozyme Based on Porphyrinic Metal-Organic Framework for Electrocatalytic CO2 Reduction

DC Field Value Language Lee, Junghye ko Choi, Hansaem ko Mun, Jinhong ko Jin, Eunji ko Lee, Soochan ko Nam, Joohan ko Umer, Muhammad ko Cho, Jaeheung ko Lee, Geunsik ko Kwon, Youngkook ko Choe, Wonyoung ko 2022-11-23T09:54:34Z - 2022-11-04 ko 2022-10 ko
dc.identifier.citation SMALL STRUCTURES ko
dc.identifier.issn 2688-4062 ko
dc.identifier.uri -
dc.description.abstract Mimicry of natural enzyme systems is an important approach for catalyst design. To create an enzyme-inspired catalyst, it is essential to mimic both the active center and the second coordination sphere. Metal-organic frameworks (MOFs), an emerging class of porous materials, are ideal candidates for heterogeneous catalysts because their versatile building blocks confer a high level of structural tunability, and the chemical environment surrounding the active center can be controlled at the molecular level. Herein, a new 2D porphyrinic MOF, PPF-100, constructed from a nonplanar saddle-distorted porphyrin linker and a Cu paddle-wheel metal node is reported. The strategic introduction of ethyl substituents allows not only to mimic the active center and second coordination sphere but also to increase the catalytic selectivity while completely inhibiting H-2 generation in the CO2 reduction reaction. ko
dc.language 영어 ko
dc.publisher WILEY ko
dc.title Nanozyme Based on Porphyrinic Metal-Organic Framework for Electrocatalytic CO2 Reduction ko
dc.type ARTICLE ko
dc.identifier.wosid 000866640300001 ko
dc.type.rims ART ko
dc.identifier.doi 10.1002/sstr.202200087 ko
Appears in Collections:
CHM_Journal Papers
ECHE_Journal Papers

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show simple item record


  • mendeley


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.