There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 18722 | - |
dc.citation.number | 36 | - |
dc.citation.startPage | 18714 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 10 | - |
dc.contributor.author | Huang, Bin | - |
dc.contributor.author | Deng, Xiangmeng | - |
dc.contributor.author | Jin, Hui | - |
dc.contributor.author | Liu, Kunming | - |
dc.contributor.author | Chen, Shanshan | - |
dc.contributor.author | Ma, Zaifei | - |
dc.contributor.author | Oh, Jiyeon | - |
dc.contributor.author | Yang, Changduk | - |
dc.contributor.author | Liu, Jinbiao | - |
dc.contributor.author | Chen, Lie | - |
dc.date.accessioned | 2023-12-21T13:41:42Z | - |
dc.date.available | 2023-12-21T13:41:42Z | - |
dc.date.created | 2022-09-15 | - |
dc.date.issued | 2022-09 | - |
dc.description.abstract | Terpolymerization is a feasible approach to optimize the device performance of organic semiconductors. Yet, since most reported terpolymers utilize a one-pot polymerization method, the regularity of the polymer backbone is severely disrupted, and the sequence structure is roughly unclear. Herein, a novel stepwise-feeding terpolymerization approach is developed to finely adjust the terpolymerization process by utilizing the merits of stereoregular donor-acceptor alternative polymerization as well as irregular random copolymerization. In the novel stepwise-feeding terpolymerization, a pre-polymer of the host polymer D18 was synthesized initially, followed by adding a third unit BDD into the polymer backbone. The obtained H9 terpolymer has a more regular main chain with a more definite sequence distribution than its analogs (H6) prepared by one-pot polymerization. As a result, the stepwise-feeding-based terpolymer H9 offered significantly reduced energy loss in the combination with the Y6 acceptor in blend, yielding a record power conversion efficiency (PCE) of up to 18.50% in the terpolymer-based organic solar cells (OSCs). The results demonstrate that stepwise terpolymerization is an effective approach to developing regular terpolymeric semiconductors for high-performance OSCs. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.10, no.36, pp.18714 - 18722 | - |
dc.identifier.doi | 10.1039/d2ta05452c | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.scopusid | 2-s2.0-85138601534 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/59325 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2022/TA/D2TA05452C | - |
dc.identifier.wosid | 000848142000001 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Optimizing sequence structures by stepwise-feeding terpolymerization for high-performance organic solar cells | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Energy & Fuels; Materials Science | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | 11-PERCENT EFFICIENCY | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | ENABLES | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.