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Lim, Hankwon
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dc.citation.startPage 116001 -
dc.citation.volume 268 - Byun, Manhee - Lee, Aejin - Cheon, Seunghyun - Kim, Heehyang - Lim, Hankwon - 2023-12-21T13:42:12Z - 2023-12-21T13:42:12Z - 2022-08-16 - 2022-09 -
dc.description.abstract Liquid organic hydrogen carriers (LOHC) are promising alternatives to conventional H-2 media owing to their novelty in the storage and transportation of H-2. Herein, a comprehensive feasibility study is reported for hydrogenation processes using several promising LOHC systems: N-ethylcarbazole (NEC)-perhydro-NEC (12H-NEC), dibenzyltoluene (DBT), perhydro-dibenzyltoluene (18H-DBT), toluene (TOL)-methylcyclohexane (MCH), and CO2-methanol (MeOH). Detailed process simulation using Aspen Plus (R) reveals a considerable amount of stored H-2 for DBT-18H-DBT (7.20 kmolH(2) h(-1)) and the lowest unit cost of H-2 storage (7.00 $ kgH(2)(-1)) by itemized cost estimation. In addition, the effects of operating temperature, recycle ratio of unreacted H-2, and scale of H-2 storage on economic feasibility are investigated, and the expected cost reductions to 2.83, 4.21, 3.84, and 2.37 $ kgH(2)(-1) are evaluated for NEC-12H-NEC, DBT-18H-DBT, TOL-MCH, and CO2-MeOH, respectively. The sensitivity analysis quantifies the variation in the total unit cost of H-2 storage and identifies the costs of the H-2 reactant and labor as key economic parameters in LOHC hydrogenation. Furthermore, 0.16-0.43, 0.78-1.72, 1.25-1.73, and 1.12-5.52 kgCO(2) kgH(2)(-1) of unit CO2 emissions are evaluated by integrative carbon footprint analysis. -
dc.identifier.bibliographicCitation ENERGY CONVERSION AND MANAGEMENT, v.268, pp.116001 -
dc.identifier.doi 10.1016/j.enconman.2022.116001 -
dc.identifier.issn 0196-8904 -
dc.identifier.scopusid 2-s2.0-85134679213 -
dc.identifier.uri -
dc.identifier.wosid 000834608600001 -
dc.language 영어 -
dc.title Preliminary feasibility study for hydrogen storage using several promising liquid organic hydrogen carriers: Technical, economic, and environmental perspectives -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Thermodynamics; Energy & Fuels; Mechanics -
dc.relation.journalResearchArea Thermodynamics; Energy & Fuels; Mechanics -
dc.type.docType Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor Liquid organic hydrogen carrier -
dc.subject.keywordAuthor Hydrogenation -
dc.subject.keywordAuthor Process simulation -
dc.subject.keywordAuthor Techno-economic analysis -
dc.subject.keywordAuthor Environmental assessment -
dc.subject.keywordPlus PERHYDRO-N-ETHYLCARBAZOLE -
dc.subject.keywordPlus METHANOL PRODUCTION -
dc.subject.keywordPlus CO2 HYDROGENATION -
dc.subject.keywordPlus SYSTEM -
dc.subject.keywordPlus DEHYDROGENATION -
dc.subject.keywordPlus CATALYSTS -
dc.subject.keywordPlus ENERGY -
dc.subject.keywordPlus MODEL -
dc.subject.keywordPlus LOHC -
dc.subject.keywordPlus FUEL -