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DC Field | Value | Language |
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dc.citation.endPage | 8006 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 7994 | - |
dc.citation.title | ACS CATALYSIS | - |
dc.citation.volume | 12 | - |
dc.contributor.author | Noh, Woo Yeong | - |
dc.contributor.author | Mun, Jinhong | - |
dc.contributor.author | Lee, Yeongdae | - |
dc.contributor.author | Kim, Eun Mi | - |
dc.contributor.author | Kim, Young Kyeong | - |
dc.contributor.author | Kim, Kwang Young | - |
dc.contributor.author | Jeong, Hu Young | - |
dc.contributor.author | Lee, Jong Hoon | - |
dc.contributor.author | Song, Hyun-Kon | - |
dc.contributor.author | Lee, Geunsik | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.date.accessioned | 2023-12-21T14:07:53Z | - |
dc.date.available | 2023-12-21T14:07:53Z | - |
dc.date.created | 2022-07-18 | - |
dc.date.issued | 2022-06 | - |
dc.description.abstract | A powerful synthetic protocol based on a molecularly engineered anchoring carbon platform (ACP) is reported to stabilize concentrated edge-hosted single-atom catalytic sites of M-N (M = Fe, Co, Ni, Cu) on carbon supports. Polymerization with L-cysteine as an additional organic precursor produces an ACP sheath around the carbon nanotube (CNT)-graphene (GR) hybrid support made of a small domain size with abundant edge sites and doped with sulfur. A few-minute-long microwave pyrolysis anchors strongly the single-atomic M-N moiety on the ACP while suppressing its agglomeration during the high-temperature synthesis and makes the ACP highly graphitized. As a typical example, the edge-hosted single-atomic catalytic sites in Fe-N/S-CNT-GR provide superior pH-independent oxygen reduction reaction (ORR) activity to previously reported Fe-N-C catalysts and commercial Pt/C while demonstrating oxygen evolution reaction (OER) activity in basic conditions similar to known state-of-the-art catalysts. In particular, the Fe-N/S-CNT-GR catalyst is much more stable than commercial Pt/C and Ir/C catalysts during ORR and OER in both base and acid solutions. Inferior stability is a common problem of this type of single-atom heterogeneous catalyst (SAC). An aqueous Zn-air battery with our Fe-N/S-CNT-GR catalyst operates as effectively as the device with the commercial Pt/C-Ir/C catalysts. We believe that our protocol based on the molecularly engineered ACP and microwave pyrolysis can provide a new concept to synthesize a new generation of durable SACs, which could have broad applications in electrochemical energy conversion and storage. | - |
dc.identifier.bibliographicCitation | ACS CATALYSIS, v.12, no.13, pp.7994 - 8006 | - |
dc.identifier.doi | 10.1021/acscatal.2c00697 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.scopusid | 2-s2.0-85134883618 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/58987 | - |
dc.identifier.wosid | 000819486300001 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Molecularly Engineered Carbon Platform To Anchor Edge-Hosted Single-Atomic M-N/C (M = Fe, Co, Ni, Cu) Electrocatalysts of Outstanding Durability | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | edge-hosted M, N, C sites | - |
dc.subject.keywordAuthor | 3D CNT | - |
dc.subject.keywordAuthor | GR hybrid | - |
dc.subject.keywordAuthor | anchoring carbon platform | - |
dc.subject.keywordAuthor | microwave pyrolysis | - |
dc.subject.keywordAuthor | oxygen reduction reaction | - |
dc.subject.keywordAuthor | Zn-air battery | - |
dc.subject.keywordAuthor | durability | - |
dc.subject.keywordPlus | OXYGEN REDUCTION REACTION | - |
dc.subject.keywordPlus | DENSITY-FUNCTIONAL THEORY | - |
dc.subject.keywordPlus | ACTIVE-SITES | - |
dc.subject.keywordPlus | REACTION CATALYSTS | - |
dc.subject.keywordPlus | FUEL-CELL | - |
dc.subject.keywordPlus | TURNOVER FREQUENCY | - |
dc.subject.keywordPlus | IRON PORPHYRINS | - |
dc.subject.keywordPlus | IDENTIFICATION | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | COORDINATION | - |
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