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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1462 | - |
dc.citation.number | 7 | - |
dc.citation.startPage | 1459 | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 8 | - |
dc.contributor.author | Min, JH | - |
dc.contributor.author | Jung, SY | - |
dc.contributor.author | Wu, B | - |
dc.contributor.author | Oh, JT | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.contributor.author | Koo, S | - |
dc.date.accessioned | 2023-12-22T10:07:48Z | - |
dc.date.available | 2023-12-22T10:07:48Z | - |
dc.date.created | 2014-09-11 | - |
dc.date.issued | 2006-03 | - |
dc.description.abstract | The R 1 substituents at C(2) of the haloallylic sulfones 1 play a pivotal role in controlling the diastereoselectivity of the indium-mediated addition reaction to benzaldehyde to produce the homoallylic alcohols 3. The R 1 Me group of 1 prefers the chair form in the In-coordinated six-membered cyclic transition state to give anti-3a, and the R 1 Ph group of 1 favors the twist boat form to give syn-3n, both in a high 13:1 selectivity. | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.8, no.7, pp.1459 - 1462 | - |
dc.identifier.doi | 10.1021/o1060297r | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.scopusid | 2-s2.0-33645920320 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5882 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33645920320 | - |
dc.identifier.wosid | 000236397000052 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Origin of the diastereoselection in the indium-mediated addition of haloallylic sulfones to aldehydes | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | STEREOSELECTIVE ALDOL CONDENSATIONS | - |
dc.subject.keywordPlus | ALPHA-HOMOALLYLIC ALCOHOLS | - |
dc.subject.keywordPlus | ORGANIC-SYNTHESIS | - |
dc.subject.keywordPlus | AQUEOUS-MEDIA | - |
dc.subject.keywordPlus | TRANSITION STRUCTURES | - |
dc.subject.keywordPlus | MECHANISTIC PROPOSAL | - |
dc.subject.keywordPlus | ALLYLATION REACTION | - |
dc.subject.keywordPlus | PROMOTED ADDITIONS | - |
dc.subject.keywordPlus | GLYOXYLIC-ACID | - |
dc.subject.keywordPlus | METAL | - |
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