BROWSE

Related Researcher

Author's Photo

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

ITEM VIEW & DOWNLOAD

Origin of the diastereoselection in the indium-mediated addition of haloallylic sulfones to aldehydes

Cited 12 times inthomson ciCited 13 times inthomson ci
Title
Origin of the diastereoselection in the indium-mediated addition of haloallylic sulfones to aldehydes
Author
Min, JHJung, SYWu, BOh, JTLah, Myoung SooKoo, S
Issue Date
2006-03
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.8, no.7, pp.1459 - 1462
Abstract
The R 1 substituents at C(2) of the haloallylic sulfones 1 play a pivotal role in controlling the diastereoselectivity of the indium-mediated addition reaction to benzaldehyde to produce the homoallylic alcohols 3. The R 1 Me group of 1 prefers the chair form in the In-coordinated six-membered cyclic transition state to give anti-3a, and the R 1 Ph group of 1 favors the twist boat form to give syn-3n, both in a high 13:1 selectivity.
URI
https://scholarworks.unist.ac.kr/handle/201301/5882
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33645920320
DOI
10.1021/o1060297r
ISSN
1523-7060
Appears in Collections:
CHM_Journal Papers
Files in This Item:
There are no files associated with this item.

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qrcode

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU