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DC Field | Value | Language |
---|---|---|
dc.citation.number | 20 | - |
dc.citation.startPage | 2200734 | - |
dc.citation.title | SMALL | - |
dc.citation.volume | 18 | - |
dc.contributor.author | Chen, Dong | - |
dc.contributor.author | Liu, Siqi | - |
dc.contributor.author | Huang, Bin | - |
dc.contributor.author | Oh, Jiyeon | - |
dc.contributor.author | Wu, Feiyan | - |
dc.contributor.author | Liu, Jiabin | - |
dc.contributor.author | Yang, Changduk | - |
dc.contributor.author | Chen, Lie | - |
dc.contributor.author | Chen, Yiwang | - |
dc.date.accessioned | 2023-12-21T14:12:22Z | - |
dc.date.available | 2023-12-21T14:12:22Z | - |
dc.date.created | 2022-05-03 | - |
dc.date.issued | 2022-05 | - |
dc.description.abstract | Developing robust materials is very critical and faces a big challenge for high-performance large-area all-polymer solar cells (all-PSCs) by printing methods. Herein, the authors combine the advantages of the terpolymerization strategy with the non-conjugated backbone strategy to regulate the molecular aggregation rationally during the film-forming printing process, facilitating a facile printing process for large-area all-PSCs. A series of terpolymer acceptors PYSe-Clx (x = 0, 10, 20, and 30) is also developed, which can effectively fine-tune the morphology and photoelectric properties of the active layer. The PBDB-T: PYSe-Cl20-based all-PSC delivers a significantly improved power cconversion efficiency (PCE) than the one with PBDB-T: PYSe (14.21% vs 12.45%). By addition of a small amount of non-conjugated polymer acceptor PTClo-Y, the ternary all-PSC reaches a PCE of 15.26%. More importantly, the regulation of molecular aggregation enables a facile blade-coating process of the large-area device. A record PCE of 13.81% for large-area devices (1.21 cm(2)) is obtained, which is the highest value for large-area all-PSCs fabricated by blade-coating. The environmentally friendly solvent processed large-area device also obtains an excellent performance of 13.21%. This work provides a simple and effective molecular design strategy of robust materials for high-performance large-area all-PSCs by a printing process. | - |
dc.identifier.bibliographicCitation | SMALL, v.18, no.20, pp.2200734 | - |
dc.identifier.doi | 10.1002/smll.202200734 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.scopusid | 2-s2.0-85128174283 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/58372 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/smll.202200734 | - |
dc.identifier.wosid | 000783023400001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Rational Regulation of the Molecular Aggregation Enables A Facile Blade-Coating Process of Large-area All-Polymer Solar Cells with Record Efficiency | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | all-polymer solar cells | - |
dc.subject.keywordAuthor | lager-area devices | - |
dc.subject.keywordAuthor | molecular aggregation | - |
dc.subject.keywordAuthor | printing | - |
dc.subject.keywordAuthor | terpolymerization strategy | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | ADDITIVE-FREE | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | ACCEPTOR | - |
dc.subject.keywordPlus | COPOLYMER | - |
dc.subject.keywordPlus | DIIMIDE | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | DONOR | - |
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