There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 18058 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 18051 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.volume | 118 | - |
dc.contributor.author | Kovarik, Libor | - |
dc.contributor.author | Bowden, Mark | - |
dc.contributor.author | Genc, Arda | - |
dc.contributor.author | Szanyi, János | - |
dc.contributor.author | Peden, Charles H. F. | - |
dc.contributor.author | Kwak, Jahun | - |
dc.date.accessioned | 2023-12-22T02:16:58Z | - |
dc.date.available | 2023-12-22T02:16:58Z | - |
dc.date.created | 2014-09-04 | - |
dc.date.issued | 2014-08 | - |
dc.description.abstract | Transition Al2O3 derived from thermal decomposition of AlOOH Boehmite have complex structures and to a large extent remain poorly understood. Here, we report a detailed atomic level analysis of δ-Al 2O3 for the first time using a combination of high-angle annular dark field electron microscopy imaging, X-ray diffraction refinement, and density functional theory calculations. We show that the structure of δ-Al2O3 represents a complex structural intergrowth from two main crystallographic variants, which are identified as δ1-Al2O3 and δ2-Al 2O3. The two main variants are fully structurally described, and in addition, we also derive their energy of formation. On the basis of comparison with other relevant transition Al2O3 phases, it is shown how energetic degeneracy leads to the structural disorder and complex intergrowths among several transition Al2O3. The results of the work have important implications for understanding thermodynamic stability and transformation processes in transition alumina. | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY C, v.118, no.31, pp.18051 - 18058 | - |
dc.identifier.doi | 10.1021/jp500051j | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.scopusid | 2-s2.0-84905841586 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5785 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84905841586 | - |
dc.identifier.wosid | 000340222300098 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Structure of δ-alumina: Toward the atomic level understanding of transition alumina phases | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.