Full metadata record
DC Field | Value | Language |
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dc.citation.endPage | 19579 | - |
dc.citation.number | 34 | - |
dc.citation.startPage | 19572 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.volume | 118 | - |
dc.contributor.author | Szilagyi, Petra Agota | - |
dc.contributor.author | Weinrauch, Ingrid | - |
dc.contributor.author | Oh, Hyunchul | - |
dc.contributor.author | Hirscher, Michael | - |
dc.contributor.author | Juan-Alcaniz, Jana | - |
dc.contributor.author | Serra-Crespo, Pablo | - |
dc.contributor.author | de Respinis, Moreno | - |
dc.contributor.author | Trzesniewski, Bartek Jacek | - |
dc.contributor.author | Kapteijn, Freek | - |
dc.contributor.author | Geerlings, Hans | - |
dc.contributor.author | Gascon, Jorge | - |
dc.contributor.author | Dam, Bernard | - |
dc.contributor.author | Grzech, Anna | - |
dc.contributor.author | van de Krol, Roel | - |
dc.date.accessioned | 2023-12-22T02:14:09Z | - |
dc.date.available | 2023-12-22T02:14:09Z | - |
dc.date.created | 2022-03-15 | - |
dc.date.issued | 2014-08 | - |
dc.description.abstract | Functionalization of metal organic frameworks results in higher hydrogen uptakes owing to stronger hydrogen host interactions. However, it has not been studied whether a given functional group acts on existing adsorption sites (linker or metal) or introduces new ones. In this work, the effect of two types of functional groups on MIL-101 (Cr) is analyzed. Thermal-desorption spectroscopy reveals that the -Br ligand increases the secondary building unit's hydrogen affinity, while the -NH2 functional group introduces new hydrogen adsorption sites. In addition, a subsequent introduction of -Br and -NH2 ligands on the linker results in the highest hydrogen-store interaction energy on the cationic nodes. The latter is attributed to a push-and-pull effect of the linkers. | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY C, v.118, no.34, pp.19572 - 19579 | - |
dc.identifier.doi | 10.1021/jp5050628 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.scopusid | 2-s2.0-84906871719 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/57851 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jp5050628 | - |
dc.identifier.wosid | 000341122200008 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Interplay of Linker Functionalization and Hydrogen Adsorption in the Metal-Organic Framework MIL-101 | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CATION-EXCHANGE | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | MOFS | - |
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