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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 8236 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 8232 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 143 | - |
dc.contributor.author | Muhammad, Raeesh | - |
dc.contributor.author | Jee, Seohyeon | - |
dc.contributor.author | Jung, Minji | - |
dc.contributor.author | Park, Jaewoo | - |
dc.contributor.author | Kang, Sung Gu | - |
dc.contributor.author | Choi, Kyung Min | - |
dc.contributor.author | Oh, Hyunchul | - |
dc.date.accessioned | 2023-12-21T15:41:10Z | - |
dc.date.available | 2023-12-21T15:41:10Z | - |
dc.date.created | 2022-03-15 | - |
dc.date.issued | 2021-06 | - |
dc.description.abstract | Adsorptive separation using narrow-micropore adsorbents has demonstrated the potential to separate hydrogen isotopes. In this work, we employed an isotope-responsive separation using cobalt formate. A D-2-responsive third sorption step was revealed, and consequently, a noticeable difference was observed in the uptakes of D-2 and H-2. This may have resulted from the additional space created for D-2 due to its dense packing, as DFT calculations revealed that cobalt formate possesses 2.26 kJ/mol higher binding strength for D-2 than for H-2. The exploitation of this D-2-responsive third sorption step renders a promising separation performance, with a D-2/H-2 selectivity of up to 44 at 25 K/1 bar. Lastly, cobalt formate was synthesized on a gram scale here, which makes it a prospect for commercialization. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.143, no.22, pp.8232 - 8236 | - |
dc.identifier.doi | 10.1021/jacs.1c01694 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-85106460214 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/57773 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jacs.1c01694 | - |
dc.identifier.wosid | 000662084400002 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Exploiting the Specific Isotope-Selective Adsorption of Metal-Organic Framework for Hydrogen Isotope Separation | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | D-2 | - |
dc.subject.keywordPlus | MIXTURE | - |
dc.subject.keywordPlus | PORES | - |
dc.subject.keywordPlus | H-2 | - |
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