dc.citation.endPage |
15583 |
- |
dc.citation.number |
43 |
- |
dc.citation.startPage |
15582 |
- |
dc.citation.title |
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
- |
dc.citation.volume |
131 |
- |
dc.contributor.author |
Manuel, Tony D. |
- |
dc.contributor.author |
Rohde, Jan-Uwe |
- |
dc.date.accessioned |
2023-12-22T07:38:14Z |
- |
dc.date.available |
2023-12-22T07:38:14Z |
- |
dc.date.created |
2014-08-28 |
- |
dc.date.issued |
2009-11 |
- |
dc.description.abstract |
(Chemical Equation Presented) Bis(imino)pyridine complex [Ni{2,6-(ArN=CMe)2C5H3N}Cl] (where Ar = 2,6-iPr2C6H3) was synthesized by reduction of the corresponding dichloride complex and characterized as a ligand-radical complex of NiII. Reaction of this complex with O 2 caused intraligand C-C bond cleavage to afford the Ni complex of the new iminoethylpyridylcarboxamidato ligand, which also was isolated as the corresponding carboxamide, 6-(ArN=CMe)C5H3N-2-C(O)NHAr. This reaction serves as an example of small-molecule activation effected directly at the redoxactive bis(imino)pyridine ligand without an overall oxidation state change at the Ni center. |
- |
dc.identifier.bibliographicCitation |
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.43, pp.15582 - 15583 |
- |
dc.identifier.doi |
10.1021/ja9065943 |
- |
dc.identifier.issn |
0002-7863 |
- |
dc.identifier.scopusid |
2-s2.0-70350641512 |
- |
dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/5732 |
- |
dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=70350641512 |
- |
dc.identifier.wosid |
000271513600008 |
- |
dc.language |
영어 |
- |
dc.publisher |
AMER CHEMICAL SOC |
- |
dc.title |
Reaction of a Redox-Active Ligand Complex of Nickel with Dioxygen Probes Ligand-Radical Character |
- |
dc.type |
Article |
- |
dc.description.journalRegisteredClass |
scopus |
- |