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Lee, Zonghoon
Atomic-Scale Electron Microscopy Lab.
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dc.citation.endPage 231 -
dc.citation.number 1 -
dc.citation.startPage 217 -
dc.citation.title CHEMISTRY OF MATERIALS -
dc.citation.volume 34 -
dc.contributor.author Gurzeda, Bartosz -
dc.contributor.author Kim, Tae In -
dc.contributor.author Arsakay, Madi -
dc.contributor.author Choe, Myeonggi -
dc.contributor.author Lee, Sun Hwa -
dc.contributor.author Lee, Zonghoon -
dc.contributor.author Min, Seung Kyu -
dc.contributor.author Ruoff, Rodney S. -
dc.date.accessioned 2023-12-21T14:42:29Z -
dc.date.available 2023-12-21T14:42:29Z -
dc.date.created 2022-01-13 -
dc.date.issued 2022-01 -
dc.description.abstract A pure stage-1 graphite intercalation compound (GIC) has been prepared by the electrochemical oxidation of graphite in trifluoroacetic acid (CF3COOH). During the CF3COOH-GIC formation, covalent as well as ionic bonds between the trifluoroacetic acid and graphite layers are formed. Electrochemical reduction of the stage-1 GIC leads to the deintercalation of ionically bonded intercalate, yielding the stage 2 covalent GIC. The interlayer spacing is 8.10 angstrom for stage-1 and 11.62 angstrom for stage-2 GIC. Further electrochemical oxidation of stage-1 CF3COOH-GIC does not lead to the exfoliation of the GIC product, and the GIC has relatively high stability in air. -
dc.identifier.bibliographicCitation CHEMISTRY OF MATERIALS, v.34, no.1, pp.217 - 231 -
dc.identifier.doi 10.1021/acs.chemmater.1c03173 -
dc.identifier.issn 0897-4756 -
dc.identifier.scopusid 2-s2.0-85122575773 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/56892 -
dc.identifier.url https://pubs.acs.org/doi/10.1021/acs.chemmater.1c03173 -
dc.identifier.wosid 000737836100001 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Electrochemical Formation of a Covalent-Ionic Stage-1 Graphite Intercalation Compound with Trifluoroacetic Acid -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Physical; Materials Science, Multidisciplinary -
dc.relation.journalResearchArea Chemistry; Materials Science -
dc.type.docType Article; Early Access -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordPlus NUCLEAR-MAGNETIC-RESONANCE -
dc.subject.keywordPlus FLUORINATED GRAPHENE -
dc.subject.keywordPlus RAMAN-SPECTROSCOPY -
dc.subject.keywordPlus ANODE MATERIALS -
dc.subject.keywordPlus NITRIC-ACID -
dc.subject.keywordPlus OXIDE -
dc.subject.keywordPlus NMR -
dc.subject.keywordPlus EXFOLIATION -
dc.subject.keywordPlus OXIDATION -
dc.subject.keywordPlus SPECTRA -

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