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DC Field | Value | Language |
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dc.citation.endPage | 231 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 217 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 34 | - |
dc.contributor.author | Gurzeda, Bartosz | - |
dc.contributor.author | Kim, Tae In | - |
dc.contributor.author | Arsakay, Madi | - |
dc.contributor.author | Choe, Myeonggi | - |
dc.contributor.author | Lee, Sun Hwa | - |
dc.contributor.author | Lee, Zonghoon | - |
dc.contributor.author | Min, Seung Kyu | - |
dc.contributor.author | Ruoff, Rodney S. | - |
dc.date.accessioned | 2023-12-21T14:42:29Z | - |
dc.date.available | 2023-12-21T14:42:29Z | - |
dc.date.created | 2022-01-13 | - |
dc.date.issued | 2022-01 | - |
dc.description.abstract | A pure stage-1 graphite intercalation compound (GIC) has been prepared by the electrochemical oxidation of graphite in trifluoroacetic acid (CF3COOH). During the CF3COOH-GIC formation, covalent as well as ionic bonds between the trifluoroacetic acid and graphite layers are formed. Electrochemical reduction of the stage-1 GIC leads to the deintercalation of ionically bonded intercalate, yielding the stage 2 covalent GIC. The interlayer spacing is 8.10 angstrom for stage-1 and 11.62 angstrom for stage-2 GIC. Further electrochemical oxidation of stage-1 CF3COOH-GIC does not lead to the exfoliation of the GIC product, and the GIC has relatively high stability in air. | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.34, no.1, pp.217 - 231 | - |
dc.identifier.doi | 10.1021/acs.chemmater.1c03173 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.scopusid | 2-s2.0-85122575773 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/56892 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.chemmater.1c03173 | - |
dc.identifier.wosid | 000737836100001 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Electrochemical Formation of a Covalent-Ionic Stage-1 Graphite Intercalation Compound with Trifluoroacetic Acid | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Materials Science | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | NUCLEAR-MAGNETIC-RESONANCE | - |
dc.subject.keywordPlus | FLUORINATED GRAPHENE | - |
dc.subject.keywordPlus | RAMAN-SPECTROSCOPY | - |
dc.subject.keywordPlus | ANODE MATERIALS | - |
dc.subject.keywordPlus | NITRIC-ACID | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | NMR | - |
dc.subject.keywordPlus | EXFOLIATION | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | SPECTRA | - |
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