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Immobilization of N and Si as center species toward microporous organic polymers for CO2 adsorption via dipole-quadrupole interaction
- Author(s)
- Zhang, Yuwei, Xie, Chao, Zhi, Yongfeng, Sun, Qikun, Luo, Xiaolong, Li, Zhongping, Wang, Jiku, Liu, Xiaoming
- Issued Date
- 2021-01
- Citation
- POLYMER, v.212, pp.123307
- Abstract
- Tailored, Ph, Si, and N as center species on microporous organic polymers (MPOPs), Ph-MPOP, Si-MPOP, and N-MPOP, were prepared through Schiff base reaction. Interestingly, MPOPs have been designed to have different N and Si center atoms that enhanced CO2 capture ability and isosteric heat through dipole-quadrupole interaction. The adsorption experiments suggested the increase of CO2 uptake values was dominated by the Si and N center decorated MPOPs.
- Publisher
- ELSEVIER SCI LTD
- ISSN
- 0032-3861
- Keyword (Author)
- Microporous organic polymers, Schiff base reaction, CO2 uptake, Dipole-quadrupole interaction
- Keyword
- CARBON-DIOXIDE, GAS-STORAGE, SURFACE-AREA, FRAMEWORKS, CAPTURE, NETWORKS, DESIGN, POLYCARBAZOLE, CONVERSION, CARBAZOLE
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