Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 6143 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 6135 | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 54 | - |
dc.contributor.author | Park, Geonhui | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-21T15:38:41Z | - |
dc.date.available | 2023-12-21T15:38:41Z | - |
dc.date.created | 2021-08-09 | - |
dc.date.issued | 2021-07 | - |
dc.description.abstract | The ring opening metathesis polymerization of cyclic allenes is described. Treating the monomers to a Grubbs-type catalyst afforded polymers that featured allenes integrated into their main chains, as confirmed through a range of spectroscopic, chromatographic, and chemical techniques. Acyclic, 1,3-disubstituted allenes were used as chain transfer agents in the aforementioned reactions. These additives not only provided the corresponding end-functionalized polymers but also enabled control over the molecular weights of the polymers produced. The polymers obtained from the ring opening metathesis polymerization reactions were transformed into silyl-containing derivatives using a hydrosilylation-based, post-polymerization modification. A polymerization mechanism was also deduced and proposed to proceed through a process that involved ruthenium vinylidene intermediates and selective chain transfer. | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.54, no.13, pp.6135 - 6143 | - |
dc.identifier.doi | 10.1021/acs.macromol.1c00571 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.scopusid | 2-s2.0-85110332691 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/55376 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.macromol.1c00571 | - |
dc.identifier.wosid | 000674278700025 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Ring Opening Metathesis Polymerization of Cyclic Allenes | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CHAIN-TRANSFER | - |
dc.subject.keywordPlus | CATIONIC-POLYMERIZATION | - |
dc.subject.keywordPlus | RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | RUTHENIUM CATALYSTS | - |
dc.subject.keywordPlus | IN-SITU | - |
dc.subject.keywordPlus | HYDROSILYLATION | - |
dc.subject.keywordPlus | ROMP | - |
dc.subject.keywordPlus | PHENYLALLENE | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | LIVING COORDINATION POLYMERIZATION | - |
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