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DC Field | Value | Language |
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dc.citation.endPage | 59914 | - |
dc.citation.number | 50 | - |
dc.citation.startPage | 59904 | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 13 | - |
dc.contributor.author | Lee, Juyeon | - |
dc.contributor.author | Lim, June Sung | - |
dc.contributor.author | Yim, Gyeonghye | - |
dc.contributor.author | Jang, Hongje | - |
dc.contributor.author | Joo, Sang Hoon | - |
dc.contributor.author | Sa, Young Jin | - |
dc.date.accessioned | 2023-12-21T14:50:18Z | - |
dc.date.available | 2023-12-21T14:50:18Z | - |
dc.date.created | 2021-12-23 | - |
dc.date.issued | 2021-12 | - |
dc.description.abstract | H2O2 electrosynthesis is an emerging clean chemical technology, whose efficiency critically depends on the activity and selectivity of electrocatalysts for two-electron oxygen reduction reaction (2e(-) ORR). Here, we demonstrate that 2e(-) ORR activity of oxygen-doped carbons, which have been one of the most promising catalysts for this reaction, can be substantially influenced by the types and concentrations of cations in electrolytes. Heat-treated carbon comprising active oxygen functional groups exhibits cation-dependent 2e(-) ORR activity trends in alkaline media, following the order Cs+ > K+ > Li+. Importantly, an electrolyte with a high cation concentration (0.1 M KOH + 0.5 M KCl) afforded the highest 2e(-) ORR mass activity (250 +/- 30 A gcat(-1) at 0.70 V vs reversible hydrogen electrode) ever reported. We have established that the cation promotion effect correlates with cation-dependent electron-transfer kinetics, which regulates the rate-determining first electron transfer to O-2. | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.13, no.50, pp.59904 - 59914 | - |
dc.identifier.doi | 10.1021/acsami.1c17727 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.scopusid | 2-s2.0-85121035828 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/55315 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acsami.1c17727 | - |
dc.identifier.wosid | 000731029600001 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Unveiling the Cationic Promotion Effect of H2O2 Electrosynthesis Activity of O-Doped Carbons | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology;Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics;Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | H2O2 electrosynthesis | - |
dc.subject.keywordAuthor | electrocatalyst | - |
dc.subject.keywordAuthor | doped carbon | - |
dc.subject.keywordAuthor | electrolyte | - |
dc.subject.keywordAuthor | double layer | - |
dc.subject.keywordAuthor | electron transfer | - |
dc.subject.keywordPlus | 2-ELECTRON OXYGEN REDUCTION | - |
dc.subject.keywordPlus | HYDROGEN-PEROXIDE | - |
dc.subject.keywordPlus | ELECTROCATALYST | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | MECHANISMS | - |
dc.subject.keywordPlus | EFFICIENCY | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | ALKALINE | - |
dc.subject.keywordPlus | TRENDS | - |
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