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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 5455 | - |
dc.citation.number | 48 | - |
dc.citation.startPage | 5453 | - |
dc.citation.title | CHEMICAL COMMUNICATIONS | - |
dc.citation.volume | 49 | - |
dc.contributor.author | Neilson, Bethany M. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T03:45:44Z | - |
dc.date.available | 2023-12-22T03:45:44Z | - |
dc.date.created | 2014-08-28 | - |
dc.date.issued | 2013-06 | - |
dc.description.abstract | The UV-induced photocyclization of a dithienylethene-annulated N-heterocyclic carbene precatalyst enabled photoswitchable ring-opening polymerizations of epsilon-caprolactone and delta-valerolactone. The polymerizations proceeded efficiently in ambient light, however UV irradiation attenuated the reaction rate (k(amb)/kUV = 59). Subsequent visible light exposure reversed the photocyclization and restored catalytic activity. | - |
dc.identifier.bibliographicCitation | CHEMICAL COMMUNICATIONS, v.49, no.48, pp.5453 - 5455 | - |
dc.identifier.doi | 10.1039/c3cc42424c | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.scopusid | 2-s2.0-84878103002 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5522 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84878103002 | - |
dc.identifier.wosid | 000319226700005 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Photoswitchable NHC-promoted ring-opening polymerizations | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENES | - |
dc.subject.keywordPlus | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | LIVING POLYMERIZATION | - |
dc.subject.keywordPlus | TRANSESTERIFICATION/ACYLATION REACTIONS | - |
dc.subject.keywordPlus | ZWITTERIONIC POLYMERIZATION | - |
dc.subject.keywordPlus | AMBIENT-TEMPERATURE | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | ORGANOCATALYSTS | - |
dc.subject.keywordPlus | ALCOHOLS | - |
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