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BielawskiChristopher W

Bielawski, Christopher W.
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dc.citation.endPage 18801 -
dc.citation.number 50 -
dc.citation.startPage 18798 -
dc.citation.title JOURNAL OF THE AMERICAN CHEMICAL SOCIETY -
dc.citation.volume 135 -
dc.contributor.author Moerdyk, Jonathan P. -
dc.contributor.author Blake, Garrett A. -
dc.contributor.author Chase, Daniel T. -
dc.contributor.author Bielawski, Christopher W. -
dc.date.accessioned 2023-12-22T03:10:54Z -
dc.date.available 2023-12-22T03:10:54Z -
dc.date.created 2014-08-28 -
dc.date.issued 2013-12 -
dc.description.abstract An N,N′-diamidocarbene (DAC) was found to activate a broad range of primary as well as secondary aliphatic and aromatic amines. The relative rates measured for the insertion of the DAC into the primary amines were consistent with an electrophilic activation mechanism; in contrast, the DAC functioned as a nucleophile upon treatment with secondary aryl amines. Collectively, these results constituted the first ambiphilic process for an isolable carbene. By comparison, an analogous diaminocarbene was found to serve exclusively as a nucleophile under similar conditions and led to the discovery of the first organic reagent to reversibly activate ammonia. -
dc.identifier.bibliographicCitation JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.135, no.50, pp.18798 - 18801 -
dc.identifier.doi 10.1021/ja411467p -
dc.identifier.issn 0002-7863 -
dc.identifier.scopusid 2-s2.0-84890781942 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/5521 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84890781942 -
dc.identifier.wosid 000328865100024 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Elucidation of Carbene Ambiphilicity Leading to the Discovery of Reversible Ammonia Activation -
dc.type Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -

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