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DC Field | Value | Language |
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dc.citation.number | 1 | - |
dc.citation.startPage | e202100757 | - |
dc.citation.title | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.citation.volume | 2022 | - |
dc.contributor.author | Cho, Sujee | - |
dc.contributor.author | Kim, Yeongjin | - |
dc.contributor.author | Lee, Soochan | - |
dc.contributor.author | Cho, Hyeonsoo | - |
dc.contributor.author | Park, Jonghoon | - |
dc.contributor.author | Hong, Doo Hwan | - |
dc.contributor.author | Kwon, Kuktae | - |
dc.contributor.author | Yoo, Hae-Wook | - |
dc.contributor.author | Choe, Wonyoung | - |
dc.contributor.author | Moon, Hoi Ri | - |
dc.date.accessioned | 2023-12-21T14:44:00Z | - |
dc.date.available | 2023-12-21T14:44:00Z | - |
dc.date.created | 2021-12-10 | - |
dc.date.issued | 2022-01 | - |
dc.description.abstract | New energetic materials are required to compensate for the shortcomings of the current ones. Especially secondary explosives are the ones with low-sensitivity, while maintaining energetic performance similar to those of primary ones, and particularly useful when safety must be ensured. Herein, we report two energetic metal-organic frameworks (eMOFs), eMOF-1, [Mn-5(mtz)(6.1)(atz)(2.9)(NO3)] (mtz=5-methyltetrazole, atz=5-aminotetrazole) and eMOF-2, [Cu(mtz)(2)], both of which have unique detonation and sensitivity properties. In particular, eMOF-1, firstly reported here, shows better energetic performance when compared with the previously reported material, Cd-based mtz MOF, an isostructural series. In addition, eMOF-2 synthesized in water shows a great detonation performance, whereas isotopological Zn-based mtz MOF did not show a meaningful performance as an explosive. Therefore, such reticular approach, i. e. replacing metal ions or ligands in isostructural frameworks, can be quite effective for the development of a new breed of energetic materials. | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, v.2022, no.1, pp.e202100757 | - |
dc.identifier.doi | 10.1002/ejic.202100757 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.scopusid | 2-s2.0-85120003766 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/55137 | - |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100757 | - |
dc.identifier.wosid | 000722805700001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Tetrazole-Based Energetic Metal-Organic Frameworks: Impacts of Metals and Ligands on Explosive Properties | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Crystal density | - |
dc.subject.keywordAuthor | Energetic material | - |
dc.subject.keywordAuthor | Metal-Organic Framework (MOF) | - |
dc.subject.keywordAuthor | Secondary explosive | - |
dc.subject.keywordAuthor | Tetrazole ligand | - |
dc.subject.keywordPlus | ZEOLITIC IMIDAZOLATE FRAMEWORKS | - |
dc.subject.keywordPlus | COORDINATION POLYMERS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | DENSITY | - |
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