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DC Field | Value | Language |
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dc.citation.endPage | 3717 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 3712 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY B | - |
dc.citation.volume | 102 | - |
dc.contributor.author | Korobov, MV | - |
dc.contributor.author | Mirakian, AL | - |
dc.contributor.author | Avramenko, NV | - |
dc.contributor.author | Valeev, EF | - |
dc.contributor.author | Neretin, IS | - |
dc.contributor.author | Slovokhotov, YL | - |
dc.contributor.author | Smith, AL | - |
dc.contributor.author | Olofsson, G | - |
dc.contributor.author | Ruoff, RS | - |
dc.date.accessioned | 2023-12-22T12:36:08Z | - |
dc.date.available | 2023-12-22T12:36:08Z | - |
dc.date.created | 2021-10-19 | - |
dc.date.issued | 1998-05 | - |
dc.description.abstract | Differential scanning calorimetry, solution calorimetry, and room-temperature single-crystal X-ray diffraction were used to study the thermodynamic and structural properties of a solvated crystal C-60. 2C(6)H(5)Br. In the monoclinic solvate, two orientations of C-60 were observed with fractional populations of 0.71 and 8.29. The enthalpy of solution of pure C-60 in bromobenzene was determined to be Delta(sol)H[C-60(s)] = -11.5 +/- -2.0 W/mol. The enthalpy of solution of the solvated crystal was Delta(sol)H[C-60. 2C(6)H(5)Br(s)] = +28 +/- 1 kJ/mol. The phase diagram of the system C-60-C6H5Br for T < 423 K was constructed. It predicts the existence of a maximum in the temperature-solubility relationship for C-60 in bromobenzene at 350 K. The activity of bromobenzene vapor over the solvated crystal is predicted to be reduced from its value over the pure liquid by a factor of 3.5. | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY B, v.102, no.19, pp.3712 - 3717 | - |
dc.identifier.doi | 10.1021/jp9804401 | - |
dc.identifier.issn | 1089-5647 | - |
dc.identifier.scopusid | 2-s2.0-0000368469 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/54528 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jp9804401 | - |
dc.identifier.wosid | 000073779400008 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | C-60 center dot bromobenzene solvate: Crystallographic and thermochemical studies and their relationship to C-60 solubility in bromobenzene | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | TEMPERATURE-DEPENDENCE | - |
dc.subject.keywordPlus | CRYSTAL | - |
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