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A Facile Route To Recover Intrinsic Graphene over Large Scale

Author(s)
Shin, Dong-WookLee, Hyun MyoungYu, Seong ManLim, Kwang-SooJung, Jae HoonKim, Min-KyuKim, Sang-WooHan, Jae-HeeRuoff, Rodney S.Yoo, Ji-Beom
Issued Date
2012-09
DOI
10.1021/nn3017603
URI
https://scholarworks.unist.ac.kr/handle/201301/54239
Fulltext
https://pubs.acs.org/doi/10.1021/nn3017603
Citation
ACS NANO, v.6, no.9, pp.7781 - 7788
Abstract
The intrinsic properties of initially p-type doped graphene (grown by chemical vapor deposition (CVD)) can be recovered by buffered oxide etch (BOE) treatment, and the dominant factor governing p-type doping is identified as the H2O/O-2 redox system. Semi-ionic C-F bonding prevents the reaction between the products of the H2O/O-2 redox system and graphene. BOE-treated graphene field effect transistors (FETs) subsequently exposed to air, became p-type doped due to recovery of the H2O/O-2 redox system. In comparison, poly(methyl methacrylate) (PMMA)-coated graphene FETs had improved stability for maintaining the intrinsic graphene electronic properties.
Publisher
AMER CHEMICAL SOC
ISSN
1936-0851
Keyword (Author)
graphenetransistorintrinsic propertiesbuffed oxide etch (BOE)PMMAH2O/O-2 redox systemFermi level
Keyword
FIELD-EFFECT TRANSISTORSSUSPENDED GRAPHENESTAINLESS-STEELSSILICON-NITRIDEREDOX COUPLEHIGH-QUALITYMOLECULESFILMSWATERCONDUCTION

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