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Yoo, Jung-Woo
Functional Hybrid Materials and Devices Lab(FHMDL)
Research Interests
  • Transport properties, spintronics, organic/molucular magnet, electronic, and spintronics,
  • 2DEG, energy harvesting device, atomic/molecular layer deposition

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Thin films of organic-based magnetic materials of vanadium and cobalt tetracyanoethylene by molecular layer deposition

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Title
Thin films of organic-based magnetic materials of vanadium and cobalt tetracyanoethylene by molecular layer deposition
Author
Kao, Chi-YuehLi, BinLu, YuYoo, Jung-WooEpstein, Arthur J.
Issue Date
2014-08
Publisher
ROYAL SOC CHEMISTRY
Citation
JOURNAL OF MATERIALS CHEMISTRY C, v.2, no.30, pp.6171 - 6176
Abstract
Thin films of Co[TCNE]x and CoxVy[TCNE] z were grown by molecular layer deposition (MLD). Metallic cobalt (Co0) was observed in the Co[TCNE]x film which contributes to the magnetism showing a coercivity of 450 Oe at 5 K with magnetic ordering temperature above 300 K. A thin film of CoxVy[TCNE] z showed magnetic ordering temperature up to 300 K with a coercivity of 50 Oe at 5 K and 30 Oe at 300 K. The film growth was monitored using a quartz crystal microbalance (QCM), and chemical compositions were characterized by X-ray photoelectron microscopy (XPS). Compared to materials previously synthesized from solution and chemical vapor deposition (CVD) methods, thin films made in this work are smooth and pinhole-free that can be beneficial for the development of thin film devices. The chemical composition of MLD-made films and the presence of Co islands are also shown here.
URI
https://scholarworks.unist.ac.kr/handle/201301/5365
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84904165409
DOI
10.1039/c4tc00673a
ISSN
2050-7526
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