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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 2473 | - |
dc.citation.number | 7 | - |
dc.citation.startPage | 2460 | - |
dc.citation.title | MATTER | - |
dc.citation.volume | 4 | - |
dc.contributor.author | Nam, Dongsik | - |
dc.contributor.author | Kim, Jiyeon | - |
dc.contributor.author | Hwang, Eunhye | - |
dc.contributor.author | Nam, Joohan | - |
dc.contributor.author | Jeong, Hyein | - |
dc.contributor.author | Kwon, Tae-Hyuk | - |
dc.contributor.author | Choe, Wonyoung | - |
dc.date.accessioned | 2023-12-21T15:38:54Z | - |
dc.date.available | 2023-12-21T15:38:54Z | - |
dc.date.created | 2021-07-29 | - |
dc.date.issued | 2021-07 | - |
dc.description.abstract | The chemical environment of pores is important for various applications of porous solids. Thanks to reticular chemistry, metal organic frameworks (MOFs) have become a versatile platform targeting numerous applications through multiple functionalizations. Although multivariate MOFs often display novel properties, identifying and manipulating pore types remain a daunting challenge. Here, we present an isoreticular series of Zr-based metal-organic polyhedra (MOPs) as a porous platform to achieve controllable intrinsic pores. Two multivariate synthetic approaches were demonstrated: a mixed-cage strategy, whereby functionalized cages are mixed, compared with the conventional mixed-linker strategy, which yields a random distribution of functionalities. A remarkable difference in functionality assembly was achieved between the strategies, with complexity increasing from binary to senary systems. More interestingly, distinct photophysical properties were observed between mixed-linker and mixed-cage samples and attributed to radiative decay kinetics. This study highlights the potential of MOPs as a unique multivariate platform with tunable component assembly to study the emerging properties of multivariate porous solids. | - |
dc.identifier.bibliographicCitation | MATTER, v.4, no.7, pp.2460 - 2473 | - |
dc.identifier.doi | 10.1016/j.matt.2021.04.027 | - |
dc.identifier.issn | 2590-2393 | - |
dc.identifier.scopusid | 2-s2.0-85108974116 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/53381 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S2590238521002198?via%3Dihub | - |
dc.identifier.wosid | 000670754800012 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER | - |
dc.title | Multivariate porous platform based on metal-organic polyhedra with controllable functionality assembly | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | COORDINATION CAGES | - |
dc.subject.keywordPlus | GAS-ADSORPTION | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | COMPLEXES | - |
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