dc.citation.endPage |
3581 |
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dc.citation.number |
10 |
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dc.citation.startPage |
3577 |
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dc.citation.title |
JOURNAL OF THE ELECTROCHEMICAL SOCIETY |
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dc.citation.volume |
146 |
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dc.contributor.author |
Cho, Jaephil |
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dc.contributor.author |
Thackeray, MM |
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dc.date.accessioned |
2023-12-22T12:10:01Z |
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dc.date.available |
2023-12-22T12:10:01Z |
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dc.date.created |
2014-07-28 |
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dc.date.issued |
1999-10 |
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dc.description.abstract |
Structural changes of LiMn2O4 spinel electrodes have been investigated in 4 V Li/LixMn2O4 cells by X-ray diffraction during prolonged electrochemical cycling between 4.5 and 3.4 V at room temperature. The capacity fade that is observed during cycling is attributed, at least partly, to disproportionation reactions at the particle surface of discharged LixMn2O4 electrodes, resulting in a soluble MnO component. The disproportionation reactions are described with respect to the Li-Mn-O phase diagram. The data support recent reports that Li2Mn2O4 can be formed at the electrode surface slightly above 3 V when cells are discharged and charged at high rates. |
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dc.identifier.bibliographicCitation |
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.146, no.10, pp.3577 - 3581 |
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dc.identifier.doi |
10.1149/1.1392517 |
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dc.identifier.issn |
0013-4651 |
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dc.identifier.scopusid |
2-s2.0-0342656159 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/5251 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0342656159 |
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dc.identifier.wosid |
000083126400007 |
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dc.language |
영어 |
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dc.publisher |
ELECTROCHEMICAL SOC INC |
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dc.title |
Structural changes of LiMn2O4 spinel electrodes during electrochemical cycling |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
- |