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DC Field | Value | Language |
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dc.citation.endPage | 4243 | - |
dc.citation.number | 27 | - |
dc.citation.startPage | 4233 | - |
dc.citation.title | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.citation.volume | 2010 | - |
dc.contributor.author | Hong, Sung You | - |
dc.contributor.author | Kreizman, Ronen | - |
dc.contributor.author | Rosentsveig, Rita | - |
dc.contributor.author | Zak, Alla | - |
dc.contributor.author | Sloan, Jeremy | - |
dc.contributor.author | Enyashin, Andrey N. | - |
dc.contributor.author | Seifert, Gotthard | - |
dc.contributor.author | Green, Malcolm L. H. | - |
dc.contributor.author | Tenne, Reshef | - |
dc.date.accessioned | 2023-12-22T06:45:05Z | - |
dc.date.available | 2023-12-22T06:45:05Z | - |
dc.date.created | 2014-07-29 | - |
dc.date.issued | 2010-09 | - |
dc.description.abstract | Various inorganic salts can be encapsulated inside the comparatively narrow (0.8-2 nm) hollow core of single-walled carbon nanotubes (SWNTs) by molten phase capillary wetting. A new synthetic strategy is presented allowing the formation of one dimensional (1D) inorganic crystals or core-shell nanotubular structures by using multiwall WS2 nanotubes as host templates. Molten phase wetting with CsI results in the formation of 1D crystal structures inside WS2 nanocapillaries with a Moire pattern. The relatively large diameter of the WS2 nanotube (with inner and outer diameters of ca. 10 and 20 nm, respectively), allows a conformal folding of the guest PbI2 layers (PbI2@WS2 core-shell nanotubes) on the interior wall of the WS2 nanotube-template, thus leading to relatively defect-free core-shell inorganic nanotubular structures, which have not been previously observed within carbon nanotubes (CNTs). Core-shell WS2@MoS2 nanotubes can be obtained by the gas-phase reaction of MoCl5 with sulfur in the presence of WS2 nanotubes. The mechanism of imbibition/solidification of the molten salt into the hollow cores of MoS2 nanotubes has been studied by molecular dynamics simulations, showing major differences between layered compounds and those with quasi-isotropic structure. Theoretical considerations also show the conditions for the stability of such core-shell 1D nanostructures. These new strategies can open up many possibilities for the synthesis of new nanotubular structures. | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, v.2010, no.27, pp.4233 - 4243 | - |
dc.identifier.doi | 10.1002/ejic.201000456 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.scopusid | 2-s2.0-77957203056 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5244 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=77957203056 | - |
dc.identifier.wosid | 000283393400003 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | One- and Two-Dimensional Inorganic Crystals inside Inorganic Nanotubes | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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