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Mechanistic investigation on the green recovery of ionic, nanocrystalline, and metallic gold by two anionic nanocelluloses

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dc.contributor.author Dwivedi, Amarendra Dhar ko
dc.contributor.author Dubey, Shashi Prabha ko
dc.contributor.author Hokkanen, Sanna ko
dc.contributor.author Sillanpaa, Mika ko
dc.date.available 2014-06-27T04:44:40Z -
dc.date.created 2014-06-25 ko
dc.date.issued 2014-10 ko
dc.identifier.citation CHEMICAL ENGINEERING JOURNAL, v.253, pp.316 - 324 ko
dc.identifier.issn 1385-8947 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/5085 -
dc.description.abstract The modified cellulose (ADAC samples) used as backbone to obtain biodegradable hydrogels, which demonstrated high affinity to concentrate precious gold species. The primary foci of the study were to develop green techniques to recover Au from dilute solutions by providing the mechanistic evidences for the adsorption coupled reduction pathways. The derivatives of anionic nanocellulose were used for recovery of the ionic, nanoparticulate, and metallic forms of Au. The ADAC samples were promising sorbing phase (57 and 60. mg/g capacity) even at low pH for the treatment of the gold-polluted waters. Thermodynamically, ADAC hydrogels were remained active at moderate to higher temperature (295-333. K) in an endothermic way. Reduction of Au occurred at different stages of kinetic curves, facilitating the formation of zerovalent gold (48 and 41. nm particle size). The Au recovery minimally altered by the competing heavy metals (Cd, Co, Cr, Ni, and As), either at equivalent or lower concentrations. A significant amount of Au(III) (83-99%) regenerated by a strong complexing eluent (0.5. M thiourea in 1. M HCl), moreover thermal crystallization yielded metallic gold in an excellent amount (94%). The mechanism of adsorptive-reduction of gold-nanocellulose were investigated and characterized by the spectroscopic studies including X-ray photoelectron spectroscopy. Overall, recovery of gold in desired forms from nanocellulose can be viewed as an effective biomaterial management strategy. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher ELSEVIER SCIENCE SA ko
dc.title Mechanistic investigation on the green recovery of ionic, nanocrystalline, and metallic gold by two anionic nanocelluloses ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84902012191 ko
dc.identifier.wosid 000340213600038 ko
dc.type.rims ART ko
dc.description.wostc 2 *
dc.description.scopustc 0 *
dc.date.tcdate 2015-05-06 *
dc.date.scptcdate 2014-06-25 *
dc.identifier.doi 10.1016/j.cej.2014.05.069 ko
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84902012191 ko
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