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DC Field | Value | Language |
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dc.citation.startPage | 105166 | - |
dc.citation.title | NANO ENERGY | - |
dc.citation.volume | 78 | - |
dc.contributor.author | Tiwari, Jitendra N. | - |
dc.contributor.author | Dang, Ngoc Kim | - |
dc.contributor.author | Park, Hyo Ju | - |
dc.contributor.author | Sultan, Siraj | - |
dc.contributor.author | Kim, Min Gyu | - |
dc.contributor.author | Haiyan, Jin | - |
dc.contributor.author | Lee, Zonghoon | - |
dc.contributor.author | Kim, Kwang S. | - |
dc.date.accessioned | 2023-12-21T16:37:59Z | - |
dc.date.available | 2023-12-21T16:37:59Z | - |
dc.date.created | 2021-02-03 | - |
dc.date.issued | 2020-12 | - |
dc.description.abstract | For the realization of commercially viable ethanol fuel cells, despite much safer than hydrogen gas, it is necessary to develop stable high-performance catalysts for ethanol electro-oxidation reaction (EOR). Unfortunately, current EOR catalysts are far from the expectation and suffer from fast activity degradation. Here we report palladium cobalt phosphide (Pd-Co2P) nanoparticles (NPs) with Pd single atoms (PdSAs) anchored on graphene oxide (GO) (denoted as Pd-Co2P-PdSAs@GO). Its EOR mass activity (10,520 mA/mgPd) is remarkably larger than any reported carbon-based precious metal catalysts including the benchmark Pd/C catalyst. To achieve high activity and stability, we systematically designed the catalyst with optimized elements ratio (Pd, Co/Ni/Fe, and P) and pyrolysis temperature together with electrochemical activation. The synergistic effect of charge-transfer between Pd and Co2P coexisting on the PdSAs@GO surface to shift the Pd d-band center promotes the bimetallic catalyst activity. The strong binding of PdSAs@GO with metals and the phosphide ligand stabilized NPs provide longterm durability. In-situ Raman analysis reveals that Co2P plays major roles in eliminating poisoning CO at neighboring Pd sites and retaining the catalytic activity even after 20 h. | - |
dc.identifier.bibliographicCitation | NANO ENERGY, v.78, pp.105166 | - |
dc.identifier.doi | 10.1016/j.nanoen.2020.105166 | - |
dc.identifier.issn | 2211-2855 | - |
dc.identifier.scopusid | 2-s2.0-85088919844 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/49995 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S2211285520307448?via%3Dihub | - |
dc.identifier.wosid | 000595907900004 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER | - |
dc.title | Remarkably enhanced catalytic activity by the synergistic effect of palladium single atoms and palladium-cobalt phosphide nanoparticles | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Electrocatalysts | - |
dc.subject.keywordAuthor | Single-atoms | - |
dc.subject.keywordAuthor | Palladium-cobalt phosphide | - |
dc.subject.keywordAuthor | Ethanol oxidation reaction | - |
dc.subject.keywordAuthor | Ethanol fuel cells | - |
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