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DC Field | Value | Language |
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dc.citation.endPage | 14156 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 14146 | - |
dc.citation.title | ACS NANO | - |
dc.citation.volume | 14 | - |
dc.contributor.author | Shang, Xiaobo | - |
dc.contributor.author | Song, Inho | - |
dc.contributor.author | Lee, Jeong Hyeon | - |
dc.contributor.author | Choi, Wanuk | - |
dc.contributor.author | Ahn, Jaeyong | - |
dc.contributor.author | Ohtsu, Hiroyoshi | - |
dc.contributor.author | Kim, Jin Chul | - |
dc.contributor.author | Koo, Jin Young | - |
dc.contributor.author | Kwak, Sang Kyu | - |
dc.contributor.author | Oh, Joon Hak | - |
dc.date.accessioned | 2023-12-21T16:47:25Z | - |
dc.date.available | 2023-12-21T16:47:25Z | - |
dc.date.created | 2021-01-08 | - |
dc.date.issued | 2020-10 | - |
dc.description.abstract | Chiral organic optoelectronics using circularly polarized light (CPL) as the key element in the photonic signal has recently emerged as a next-generation photonic technology. However, it remains challenging to simultaneously achieve high polarization selectivity and superior optoelectronic performance. Supramolecular two-dimensional (2D) chiral organic single crystals may be, good candidates for this purpose due to their defect-free nature, molecular diversity, and morphologies. Here, quasi-2D single crystals of chiral perylene diimides with parallelogram and triangle/hexagon morphologies have been selectively fabricated via self-assembly using different cosolvent systems. These materials exhibit amplified circular dichroism (CD) spectral signals, due to their molecular packing modes and supramolecular chirality. Through molecular surface n-doping using hydrazine, chiral single crystals exhibit electron mobility surpassing 1.0 cm(2) V-1 s(-1), which is one of the highest among chiral organic semiconductors, and excellent optoelectronic functions. Theoretical calculations reveal that the radical anions formed by n-doping increase the electron affinity and/or reduce the energy gap, thus facilitating electron transport. More importantly, the doped organic chiral crystals selectively discriminate CPL handedness with a high anisotropy factor of photoresponsivity (similar to 0.12). These results demonstrate that surface-doped quasi-2D chiral organic single crystals are highly promising for chiral optoelectronics | - |
dc.identifier.bibliographicCitation | ACS NANO, v.14, no.10, pp.14146 - 14156 | - |
dc.identifier.doi | 10.1021/acsnano.0c07012 | - |
dc.identifier.issn | 1936-0851 | - |
dc.identifier.scopusid | 2-s2.0-85095401636 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/49506 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acsnano.0c07012 | - |
dc.identifier.wosid | 000586793400161 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Surface-Doped Quasi-2D Chiral Organic Single Crystals for Chiroptical Sensing | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | supramolecular chirality | - |
dc.subject.keywordAuthor | quasi-2D organic single crystals | - |
dc.subject.keywordAuthor | optoelectronics | - |
dc.subject.keywordAuthor | circularly polarized light detection | - |
dc.subject.keywordAuthor | hydrazine doping | - |
dc.subject.keywordPlus | SUPRAMOLECULAR CHIRALITY | - |
dc.subject.keywordPlus | PYRONIN-B | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | DIIMIDE | - |
dc.subject.keywordPlus | TRANSISTOR | - |
dc.subject.keywordPlus | NANOWIRES | - |
dc.subject.keywordPlus | MOLECULES | - |
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