Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 11698 | - |
dc.citation.number | 43 | - |
dc.citation.startPage | 11692 | - |
dc.citation.title | CHEMICAL SCIENCE | - |
dc.citation.volume | 11 | - |
dc.contributor.author | Park, Sodam | - |
dc.contributor.author | Kristanto, Imanuel | - |
dc.contributor.author | Jung, Gwan Yeong | - |
dc.contributor.author | Ahn, David B. | - |
dc.contributor.author | Jeong, Kihun | - |
dc.contributor.author | Kwak, Sang Kyu | - |
dc.contributor.author | Lee, Sang-Young | - |
dc.date.accessioned | 2023-12-21T16:43:19Z | - |
dc.date.available | 2023-12-21T16:43:19Z | - |
dc.date.created | 2020-11-30 | - |
dc.date.issued | 2020-11 | - |
dc.description.abstract | Despite their potential as promising alternatives to current state-of-the-art lithium-ion batteries, aqueous rechargeable Zn-ion batteries are still far away from practical applications. Here, we present a new class of single-ion conducting electrolytes based on a zinc sulfonated covalent organic framework (TpPa-SO3Zn0.5) to address this challenging issue. TpPa-SO3Zn0.5 is synthesised to exhibit single Zn2+ conduction behaviour via its delocalised sulfonates that are covalently tethered to directional pores and achieve structural robustness by its beta-ketoenamine linkages. Driven by these structural and physicochemical features, TpPa-SO3Zn0.5 improves the redox reliability of the Zn metal anode and acts as an ionomeric buffer layer for stabilising the MnO2 cathode. Such improvements in the TpPa-SO3Zn0.5-electrode interfaces, along with the ion transport phenomena, enable aqueous Zn-MnO2 batteries to exhibit long-term cyclability, demonstrating the viability of COF-mediated electrolytes for Zn-ion batteries. | - |
dc.identifier.bibliographicCitation | CHEMICAL SCIENCE, v.11, no.43, pp.11692 - 11698 | - |
dc.identifier.doi | 10.1039/d0sc02785e | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.scopusid | 2-s2.0-85096035127 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48851 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2020/SC/D0SC02785E#!divAbstract | - |
dc.identifier.wosid | 000588192000027 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A single-ion conducting covalent organic framework for aqueous rechargeable Zn-ion batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | LITHIUM-ION | - |
dc.subject.keywordPlus | LONG-LIFE | - |
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