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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3933 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 3931 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 47 | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Van Heuvelen, Katherine M. | - |
dc.contributor.author | Yap, Glenn P. A. | - |
dc.contributor.author | Brunold, Thomas C. | - |
dc.contributor.author | Riordan, Charles G. | - |
dc.date.accessioned | 2023-12-22T08:40:08Z | - |
dc.date.available | 2023-12-22T08:40:08Z | - |
dc.date.created | 2020-09-01 | - |
dc.date.issued | 2008-05 | - |
dc.description.abstract | Activation of elemental sulfur by the monovalent nickel complex [PhTt(tBu)]Ni(CO) [PhTt(tBu) = phenyl{tris[(tert-butylmethyl)thio]methyl}borate] generates the disulfidodinickel(II) complex 2. This species is alternatively accessible via thermal decomposition of [PhTt(tBu)]Ni(SCPh3). Spectroscopic, magnetic, and X-ray diffraction studies establish that 2 contains a mu-eta(2):eta(2)-S-2 ligand that fosters antiferromagnetic exchange coupling between the Ni-II ions. This observation is in contrast to the lighter congener, oxygen, which strongly favors the bis(mu-oxo)dinickel(III) structure. 2 oxidizes, PPh3 to SPPh3 and reacts with 02, generating several products, one of which has been identified as [(PhTt(tBu))Ni](2)(mu-S) (3). | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.47, no.10, pp.3931 - 3933 | - |
dc.identifier.doi | 10.1021/ic800321x | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.scopusid | 2-s2.0-44349083132 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48156 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ic800321x | - |
dc.identifier.wosid | 000255770400004 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | New synthetic routes to a disulfidodinickel(II) complex: Characterization and reactivity of a Ni-2(mu-eta(2):eta(2)-S-2) core | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | DIOXYGEN ACTIVATION | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | DISULFIDE COMPLEX | - |
dc.subject.keywordPlus | DONOR LIGANDS | - |
dc.subject.keywordPlus | SIDE-ON | - |
dc.subject.keywordPlus | NICKEL | - |
dc.subject.keywordPlus | SULFUR | - |
dc.subject.keywordPlus | THIOLATE | - |
dc.subject.keywordPlus | CLUSTERS | - |
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