There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 2241 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 2234 | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 40 | - |
dc.contributor.author | Choi, Yu Jin | - |
dc.contributor.author | Cho, Kyung-Bin | - |
dc.contributor.author | Kubo, Minoru | - |
dc.contributor.author | Ogura, Takashi | - |
dc.contributor.author | Karlin, Kenneth D. | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.accessioned | 2023-12-22T06:14:19Z | - |
dc.date.available | 2023-12-22T06:14:19Z | - |
dc.date.created | 2020-09-01 | - |
dc.date.issued | 2011-03 | - |
dc.description.abstract | A copper(II)–hydroperoxo complex, [Cu(Me6-tren)(OOH)]+ (2), and a copper(II)–cumylperoxo complex, [Cu(Me6-tren)(OOC(CH3)2Ph)]+ (3), were synthesized by reacting [Cu(Me6-tren)(CH3CN)]2+ (1) with H2O2 and cumyl-OOH, respectively, in the presence of triethylamine. These intermediates, 2 and 3, were successfully characterized by various physicochemical methods such as UV-vis, ESI-MS, resonance Raman and EPR spectroscopies, leading us to propose structures of the Cu(II)–OOR species with a trigonal-bipyramidal geometry. Density functional theory (DFT) calculations provided geometric and electronic configurations of 2 and 3, showing trigonal bipyramidal copper(II)–OOR geometries. These copper(II)–hydroperoxo and –cumylperoxo complexes were inactive in electrophilic and nucleophilic oxidation reactions. | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.40, no.10, pp.2234 - 2241 | - |
dc.identifier.doi | 10.1039/c0dt01036g | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.scopusid | 2-s2.0-79951879414 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48143 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2011/DT/c0dt01036g#!divAbstract | - |
dc.identifier.wosid | 000287665000023 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Spectroscopic and computational characterization of Cu-II-OOR (R = H or cumyl) complexes bearing a Me-6-tren ligand | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.