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DC Field | Value | Language |
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dc.citation.endPage | 3033 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 3023 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 23 | - |
dc.contributor.author | Jeong, Ah Rim | - |
dc.contributor.author | Shin, Jong Won | - |
dc.contributor.author | Jeong, Jong Hwa | - |
dc.contributor.author | Bok, Kwon Hee | - |
dc.contributor.author | Kim, Cheal | - |
dc.contributor.author | Jeong, Donghyun | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Hayami, Shinya | - |
dc.contributor.author | Min, Kil Sik | - |
dc.date.accessioned | 2023-12-21T22:37:05Z | - |
dc.date.available | 2023-12-21T22:37:05Z | - |
dc.date.created | 2020-09-03 | - |
dc.date.issued | 2017-03 | - |
dc.description.abstract | Dinuclear Fe-III and Ni-II complexes, [(phen-O)Fe(N-3)](2)(NO3)(2) (1) and [(phenOH)Ni(N-3)(2)](2) (2), were prepared by treating Fe(NO3)(3)center dot 9H(2)O and Ni(NO3)(2)center dot 6H(2)O in methanol, respectively, with phenOH (=N-(2-pyridylmethyl)-N'-(2-hydroxyethyl)ethylenediamine) and NaN3; both 1 and 2 were characterized by elemental analysis, IR spectroscopy, X-ray diffraction, and magnetic susceptibility measurements. Two ethoxo-bridged Fe-III and two azido-bridged Ni-II were ob-served in 1 and 2, respectively; corresponding antiferromagnetic interaction via the bridged ethoxo groups and strong ferromagnetic coupling via the bridged end-on azido ligands within the dimeric unit were observed. Complex 1 did not exhibit any catalytic activity, while 2 exhibited excellent catalytic activities for the epoxidation of aliphatic, aromatic, and terminal olefins. | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.23, no.13, pp.3023 - 3033 | - |
dc.identifier.doi | 10.1002/chem.201604498 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.scopusid | 2-s2.0-85012095903 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48109 | - |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201604498 | - |
dc.identifier.wosid | 000395774700009 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Dinuclear Iron(III) and Nickel(II) Complexes Containing N-(2-Pyridylmethyl)-N '-(2-hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | catalysis | - |
dc.subject.keywordAuthor | coordination complexes | - |
dc.subject.keywordAuthor | crystal structure | - |
dc.subject.keywordAuthor | magnetic properties | - |
dc.subject.keywordAuthor | tetradentate ligands | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | INDUCED ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | TERMINAL OLEFINS | - |
dc.subject.keywordPlus | ALKANE-HYDROXYLATION | - |
dc.subject.keywordPlus | NI-II | - |
dc.subject.keywordPlus | ALKENE EPOXIDATION | - |
dc.subject.keywordPlus | HYDROGEN-PEROXIDE | - |
dc.subject.keywordPlus | SPIN-CROSSOVER | - |
dc.subject.keywordPlus | M-CPBA | - |
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