There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 7768 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 7764 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 57 | - |
dc.contributor.author | Jeong, Donghyun | - |
dc.contributor.author | Yan, James J. | - |
dc.contributor.author | Noh, Hyeonju | - |
dc.contributor.author | Hedman, Britt | - |
dc.contributor.author | Hodgson, Keith O. | - |
dc.contributor.author | Solomon, Edward I. | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.date.accessioned | 2023-12-21T20:39:03Z | - |
dc.date.available | 2023-12-21T20:39:03Z | - |
dc.date.created | 2020-09-03 | - |
dc.date.issued | 2018-06 | - |
dc.description.abstract | Naphthalene oxidation with metal-oxygen intermediates is a difficult reaction in environmental and biological chemistry. Herein, we report that a Mn-IV bis(hydroxo) complex, which was fully characterized by various physicochemical methods, such as ESI-MS, UV/Vis, and EPR analysis, X-ray diffraction, and XAS, can be employed for the oxidation of naphthalene in the presence of acid to afford 1,4-naphthoquinone. Redox titration of the Mn-IV bis(hydroxo) complex gave a one-electron reduction potential of 1.09 V, which is the most positive potential for all reported nonheme Mn-IV bis(hydroxo) species as well as Mn-IV oxo analogue& Kinetic studies, including kinetic isotope effect analysis, suggest that the naphthalene oxidation occurs through a rate-determining electron transfer process. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.26, pp.7764 - 7768 | - |
dc.identifier.doi | 10.1002/anie.201802641 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-85048770545 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48103 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201802641 | - |
dc.identifier.wosid | 000435766800031 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | manganese | - |
dc.subject.keywordAuthor | metal-hydroxo compounds | - |
dc.subject.keywordAuthor | naphthalene | - |
dc.subject.keywordAuthor | oxidation | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordPlus | COUPLED ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | NONHEME IRON(IV)-OXO COMPLEX | - |
dc.subject.keywordPlus | HYDROGEN-ATOM ABSTRACTION | - |
dc.subject.keywordPlus | METAL OXO | - |
dc.subject.keywordPlus | MULTIELECTRON OXIDATION | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | BRIDGED CYCLAM | - |
dc.subject.keywordPlus | OXYGEN SOURCE | - |
dc.subject.keywordPlus | TRIFLIC ACID | - |
dc.subject.keywordPlus | REACTIVITY | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.