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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 16041 | - |
dc.citation.number | 47 | - |
dc.citation.startPage | 16037 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 140 | - |
dc.contributor.author | Jeong, Donghyun | - |
dc.contributor.author | Ohta, Takehiro | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.date.accessioned | 2023-12-21T19:52:38Z | - |
dc.date.available | 2023-12-21T19:52:38Z | - |
dc.date.created | 2020-09-03 | - |
dc.date.issued | 2018-11 | - |
dc.description.abstract | Transition metal-iodosylarene complexes have been proposed to be key intermediates in the catalytic cycles of metal catalysts with iodosylarene. We report the first X-ray crystal structure and spectroscopic characterization of a mononuclear nonheme manganese-(III)-iodosylarene complex with a tetradentate macro cyclic ligand, [Mn-III(TBDAP)(OIPh)(OH)](2+) (2). The manganese(III) iodosylarene complex is capable of conducting various oxidation reactions with organic substrates, such as C-H bond activation, sulfoxidation and epoxidation. Kinetic studies including isotope labeling experiments and Hammett correlation demonstrate the electrophilic character on the Mn-iodosylarene adduct. This novel intermediate would be prominently valuable for expanding the chemistry of transition metal catalysts. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.140, no.47, pp.16037 - 16041 | - |
dc.identifier.doi | 10.1021/jacs.8b10244 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-85057269910 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48101 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jacs.8b10244 | - |
dc.identifier.wosid | 000451933100010 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Structure and Reactivity of a Mononuclear Nonheme Manganese(III)-Iodosylarene Complex | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | MULTIPLE ACTIVE OXIDANTS | - |
dc.subject.keywordPlus | DIOXYGEN ACTIVATION | - |
dc.subject.keywordPlus | HYPERVALENT IODINE | - |
dc.subject.keywordPlus | OXYGEN-TRANSFER | - |
dc.subject.keywordPlus | ATOM TRANSFER | - |
dc.subject.keywordPlus | IRON | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | MANGANESE | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | IRON(III) | - |
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