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Song, Hyun-Kon
eclat: ElectroChemistry Lab of Advanced Technology
Research Interests
  • Electrochemical analysis, electroactive materials, electrochemistry-based energy devices


Programming galvanostatic rates for fast-charging lithium ion batteries: A graphite case

DC Field Value Language Ko, Younghoon ko Cho, Yoon-Gyo ko Song, Hyun-Kon ko 2014-04-30T05:26:59Z - 2014-04-30 ko 2014-03 ko
dc.identifier.citation RSC ADVANCES, v.4, no.32, pp.16545 - 16550 ko
dc.identifier.issn 2046-2069 ko
dc.identifier.uri -
dc.description.abstract Galvanostatically induced lithiation of graphite, as a cathodic process of lithium ion batteries during charging, was investigated in situ by galvanostatic electrochemical impedance spectroscopy (GS-EIS). When lithiation is driven by charge rates slow enough for kinetics of the lithiation process to be considered relatively sluggish, charge transfer resistance (RCT) is slightly reduced as lithium ion intercalation proceeds from the dilute stage to stage 2L. Subsequently, RCT begins to increase during transformation of stage 2L to stage 2, followed by an abrupt increase in RCT observed during transition from stage 2 to stage 1, or after the inter-space of graphites is fully filled with lithium ions. As the ratio of charge rate to lithiated graphite increases, the potential responsible for the transition from stage 2L to stage 2 is shifted to more negative values due to significant polarization. Simultaneously, cells reach cut-off potentials before the transition from stage 2 to stage 1 proceeds. Based on the information regarding RCT profiles obtained by galvanostatic charging processes, a charging strategy is programmed with several different charge rates (C-rates). The capacity of lithiation is significantly enhanced by a C-rate switching (CRS) strategy. As a representative example, 75% of available capacity is charged for 50 minutes by a combination of 2 C, 1 C, and 0.5 C. However, only 12% and 51% of graphite is lithiated within the same time duration by a single charge rate of 0.1 C and 0.5 C, respectively. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher ROYAL SOC CHEMISTRY ko
dc.title Programming galvanostatic rates for fast-charging lithium ion batteries: A graphite case ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84897971062 ko
dc.identifier.wosid 000335016400023 ko
dc.type.rims ART ko
dc.description.wostc 0 *
dc.description.scopustc 0 * 2014-10-18 * 2014-07-12 *
dc.identifier.doi 10.1039/c4ra01662a ko
dc.identifier.url!divAbstract ko
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